Skip to main content
Log in

Impact fracture behaviour of double-base gun propellants

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Impact fracture properties of three nitrocellulose—nitroglycerine gun propellants have been measured in a three-point bend mode at moderate impact rates with an instrumented drop-weight impact tester. Dynamic moduli and loss tangents were measured over the temperature range −100 to +120° C, and three transitions were identified. A transition at about −30° C was found to increase the low-temperature fracture toughness of the higher nitroglycerine content propellants. The fracture data were analysed in terms of plane stress and plane strain fracture modes using a simplified model. It was found that the fracture toughness in zones undergoing plastic deformation under plane stress conditions was approximately twice that in zones under plane strain conditions. The plastic zone radii were greater than 0.3 mm at 20° C, falling to about 0.1 mm at −45° C. Strain energy release rates were calculated from fracture load and modulus, and from fracture energy. Good agreement was obtained between the two methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. J. Kinloch and R. A. Gledhill, International Conference on Nitrocellulose Characterisation, Propellants Explosives and Rocket Motor Establishment, Waltham Abbey, UK, May 1980.

  2. R. A. Gledhill, A. J. Kinloch, Propell. Explos. 4 (1979) 73.

    Article  CAS  Google Scholar 

  3. J. E. Srawley, “Fracture”, Vol. 4, edited by H. Liebowitz (Academic, New York, 1969) p. 63.

    Google Scholar 

  4. H. R. Brown, J. Mater. Sci. 8 (1973) 941.

    Article  CAS  Google Scholar 

  5. G. P. Marshall, J. G. Williams and C. E. Turner, ibid. 8 (1973) 949.

    Article  CAS  Google Scholar 

  6. E. Plati and J. G. Williams, Polym. Eng. Sci. 15 (1975) 470.

    Article  CAS  Google Scholar 

  7. M. Parvin and J. G. Williams, Int. J. Fract. 11 (1975) 963.

    CAS  Google Scholar 

  8. L. V. Newmann and J. G. Williams, Polym. Eng. Sci. 20 (1980) 572.

    Article  CAS  Google Scholar 

  9. O. F. Yap, Y. W. Mai and B. Cotterell, J. Mater. Sci. 18 (1983) 657.

    Article  CAS  Google Scholar 

  10. I. M. Ward, ibid. 6 (1971) 1397.

    Article  CAS  Google Scholar 

  11. D. J. Townsend and R. C. Warren, Polymer in press.

  12. S. Venzi, A. H. Priest and M. J. May, ASTM STP 466 (American Society for Testing and Materials, Philadelphia, 1970) p. 165.

    Google Scholar 

  13. O. L. Davies, (ed.), “Statistical Methods in Research and Production” (Oliver and Boyd, London, 1961).

    Google Scholar 

  14. R. F. Boyer, Polymer 17 (1976) 996.

    Article  CAS  Google Scholar 

  15. B. Hartmann and G. F. Lee, J. Appl. Polym. Sci. 23 (1979) 3639.

    Article  CAS  Google Scholar 

  16. B. Hartmann and G. F. Lee, J. Appl. Polym. Sci. 23 (1979) 3639.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Warren, R.C. Impact fracture behaviour of double-base gun propellants. J Mater Sci 20, 3131–3140 (1985). https://doi.org/10.1007/BF00545178

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00545178

Keywords

Navigation