Conclusions
Using calculation methods based on the chemical structure of molecules, characteristic constants of ε-caprolactam which are missing from the literature have been calculated.
On the basis of the principle of corresponding states, using characteristic constants, the thermodynamic characteristics of caprolactam have been refined and determined anew (pressure, heat of vaporization, and heat capacity) over a wide temperature range.
Similar content being viewed by others
Literature cited
R. Reed, J. Prausnitz, and J. Sherwood, Properties of Gases and Liquids [Russian translation], Khimiya, Leningrad (1982).
K. E. Fishman and N. A. Khurzin, Production of Kapron Fibre [in Russian], Khimiya, Moscow (1976).
L. A. Vol'f and B. Sh. Khaitin, Polycaproamide Manufacture [in Russian], Khimiua, Moscow (1979).
Yu. A. Soldatenko and L. I. Tarabrova, in: Thermophysical Properties of Substances [in Russian], Naukova Dumka, Kiev (1966), pp. 165–173.
V. I. Ovchinniko and V. R. Ruchinskii (eds.), Caprolactam Manufacture [in Russian], Khimiya, Moscow (1977).
I. M. Vlasov, O. K. Gubanova, and V. B. Kvasha, Khim. Volokna, No. 1, 18–19 (1983).
K. Riggert and F. Terrier, Chem. Techn., 2, No. 3, 95–99 (1973).
V. P. Kolesov, E. E. Paukov, et al., Dokl. Akad. Nauk SSSR, 128, No. 1, 130–132 (1959).
A. G. Korachevskii and V. E. Sabinin, Zh. Prikl. Khim., 33, No. 8, 1775–1779 (1960).
Additional information
Translated from Khimicheskie Volokna, No. 1, pp. 20–22, January–February, 1988.
Rights and permissions
About this article
Cite this article
Vlasov, I.M., Lednik, V.F., Gubanova, O.K. et al. Calculation of some thermodynamic characteristics of ε-caprolactam. Fibre Chem 20, 25–28 (1988). https://doi.org/10.1007/BF00544755
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00544755