Abstract
This review summarizes current descriptions of the science and technology of graphite manufacture. The delayed coking process is outlined and mechanisms of coke formation put forward including considerations of the composition of feedstocks. As graphite manufacture uses calcined delayed cokes of which the most valuable is needle-coke, a comparison of rotary kiln, rotary hearth and vertical shaft calciners is made. Grinding and sizing of calcined coke is important as this with the binder pitch leads to baked carbon. The stages in the manufacturing process are described as mixing, forming, extrusion, moulding, baking, impregnation and graphitization. The more advanced processing technology includes isostatic hot pressing, artifact densifications, high pressure impregnation/baking and binderless graphitization. A comprehensive list of references is included.
Similar content being viewed by others
References
C. L. Mantell, “Carbon and Graphite Handbook” (Wiley Interscience, New York, 1968) Chap. 15.
J. M. Hutcheon, in “Modern Aspects of Graphite Technology”, edited by L. C. F. Blackman (Academic Press, London, 1970) Chap. 2.
J. M. Meers, “Encyclopaedia of Chemical Technology” Vol. 4, 3rd edn. (John Wiley and Sons, New York, 1978) p. 589.
I. C. Lewis and L. S. Singer, “Chemistry and Physics of Carbon”, Vol. 17, edited by P. L. Walker Jr and P. A. Thrower (Marcel Dekker, New York, 1981) p. 1.
H. Marsh and P. L. Walker Jr, “Chemistry and Physics of Carbon” Vol. 15, edited by P. L. Walker Jr and P. A. Thrower (Marcel Dekker, New York, 1979) p. 229.
C. B. Scott, “Chemical and Industry” (S.C.I., London, 1967) p. 1124.
N. P. Lieberman, Oil Gas J. 78 (1980) 71.
J. W. Stadelhofer, R. Marrett and W. Gemmeke, Fuel 60 (1981) 877.
T. Reis, Hydrocarbon Process. 54 (1975) 97.
B. Alberts and D. P. Zwartbol, Oil Gas J. 77 (1979) 137.
A. J. Gambro, D. T. Shedd, H. W. Wang and T. Yoshida, Chem. Eng. Prog. 65 (1969) 75.
W. J. Metrailer, R. C. Royle and G. C. Lahn, “Petroleum Derived Carbons” in ACS Symposia Series No. 21, edited by M. L. Deviney and T. M. O'Grady (ACS, Washington, 1976) Chap. 3.
R. G. Busch, Oil Gas J. 68 (1970) 102.
J. D. Brooks and G. H. Taylor, “Chemistry and Physics of Carbon” Vol. 4, edited by P. L. Walker Jr (Edward Arnold, New York, 1964) p. 243.
M. P. Whittaker and L. I. Grindstaff, Carbon 10 (1972) 397.
J. L. White, “Petroleum Derived Carbons” in ACS Symposia Series No. 21, edited by M. L. Deviney and T. M. O'Grady (ACS Washington, 1976) Chap. 21.
H. Yamasaki, H. Tanaka and K. Noguchi, Extended Abstracts, CARBON '80, Baden-Baden, Germany, June 1980 (D.K.G., 1980) p. 393.
J. C. Lewis and T. Edstrom, J. Org. Chem. 28 (1963) 2050.
D. M. Riggs and R. J. Diefendorf, Extended Abstracts, CARBON '80, Baden-Baden, Germany, June 1980 (D.K.G., 1980) p. 326.
R. T. Lewis, Extended Abstracts of 12th Biennial Conference on Carbon, June (Pittsburgh, USA, 1975) p. 215.
H. Marsh and C. Cornford, “Petroleum Derived Carbons” in ACS Symposia Series No. 21, edited by M. L. Deviney and T. M. O'Grady (ACS, Washington, 1976) Chap. 20.
H. Marsh and J. Smith, “Analytical Methods for Coal and Coal Products”, edited by C. Karr Jr, II (Academic Press, New York, 1978) Chap. 30, pp. 371–414.
H. Honda, H. Kimura and Y. Sanada, Carbon 9 (1971) 695.
P. L. Walker Jr, ibid. 10 (1972) 369.
M. Buechler, C. B. Ng and J. L. White, Extended Abstracts of 14th Biennial Conference on Carbon, University Park, PA, USA, June 1979 (American Carbon Society) p. 433.
M. Beuchler, C.B. NG and J. L. White, Extended Abstracts of 15th Biennial Conference on Carbon, June Philadelphia, USA, June 1981) (American Carbon Society) p. 182.
I. Lang and P. Vaurecka, Fuel 60 (1981) 1176.
R. R. Jakob, Hydrocarbon Process. 50 (1971) 132.
S. E. Moschopedis and J. G. Speight, Fuel 57 (1978) 25.
J. H. Gary and G. E. Handwork, “Petroleum Refining Technology and Economics”, in Chemical Processing and Engineering, Vol. 5 (Marcel Dekker, New York, 1975) Chap. 1.
Y. Takegami, Y. Watanabe, T. Suzuki, T. Mitusudo and M. Itoh, Fuel 59 (1980) 253.
E. M. Dickinson, ibid. 59 (1980) 290.
K. S. Seshadri, E. W. Albaugh and J. D. Bacha, ibid. 61 (1982) 336.
K. W. Tucker and L. A. Joo, Extended Abstracts of 14th Biennial Conference on Carbon, University Park, PA, USA, June 1979 (American Carbon Society) p. 379.
R. W. Wallouch and F. V. Fair, Carbon 18 (1980) 147.
O. J. Horne and C. R. Kennedy, “Petroleum Derived Carbons” in ACS Symposia Series No. 21, edited by M. L. Deviney and T. M. O'Grady (ACS, Washington, 1976) Chap. 12.
J. H. Smith, Manufacture of Petroleum Coke, US Patent 3173 852 Conoco, March 16th (1965).
W. J. Kemnitzer and C. D. Edgerton, USBM Information circular, 8259, US Department of Interior (1965).
J. B. Taggart, Preprint No. 62-F24 AIME, National Meeting, New York (February 1962).
H. Tillman, U. Braun and H. Pauls, Extended Abstracts of 15th Biennial Conference on Carbon, Philadelphia, USA, June 1981 (American Carbon Society) p. 443.
F. Manzillo, S. O. Moreno L. M. C. Sze and W. V. Bauer, Hydrocarbon Process. 54 (1975) 145.
Conoco Patent; Calcining particulate carbonaceous material in an internally-fired vertical shaft kiln particularly delayed petroleum coke. US Patent 4251-323, Conoco Inc., 16th April (1979).
T. Reis, Hydrocarbon Process. 54 (1975) 145.
C. A. Stokes, “Petroleum Derived Carbons”, in ACS Symposia Series No. 21, edited by M. L. Deviney and T. M. O'Grady (ACS Washington, 1976) Chap. 1.
A. H. M. Andreasen, “Fineness of Solids” Vol. 3 (Ingeniorvidensk Skrif, Denmark, 1939).
P. Bergognon, J. Bentolila, P. Cornuault and M. S. T. Price, Proceedings of 2nd Conference on Industrial Carbons and Graphites, London, September 1966 (S.C.I., London, 1966) p. 456.
F. Rusinko and W. E. Parker, Fuel 41 (1962) 275.
C. R. Mason, Proceedings of 5th London International Conference on Carbon and Graphite, September (S.C.I. London 1978) p. 344.
G. Moutard, J. Millet and J. Parisot, Proceedings of 5th June Biennial Conference on Carbon Vol. 1, University Park, PA USA, June 1961 (Pergamon Press, New York, 1962) pp. 509–515.
S. Yamada, ibid. Vol. 2, p. 431.
R. Balduhn, R. Busch, E. Fitzer and T. Trendelenburg, Extended Abstracts of 15th Biennial Conference on Carbon Philadelphia, USA, June 1981 (American Carbon Society) p. 170.
L. F. King and W. D. Robertson, Fuel 47 (1968) 197.
C. H. Riesz and S. Susman, Proceedings of 4th Biennial Conference on Carbon, Buffalo USA, June 1960 (American Carbon Society) p. 609.
P. Wagner and L. B. Dauelsberg, Carbon 7 (1969) 273.
D. Mcneil and L. J. Wood, Proceedings of 1st Conference on Industrial Carbons and Graphite, London, September 1958 (S.C.I., London, 1958) p. 162.
R. E. Nightingale, “Nuclear Graphite” (Academic Press, New York, 1962) Chap. 2.
M. Born, Fuel 53 (1974) 198.
L. W. Graham and M. S. T. Price, Proceedings of 2nd Conference and Industrial Carbons and Graphites, September (S.C.I. London 1966) p. 466.
D. A. Boyland, British Patent 915062 (1963).
K. Ikeda, K. Kawasoe and Y. Fukuda, Symposium on Carbon, Paper No. 7 (Carbon Society of Japan, Tokyo, 1964).
E. G. Acheson, Pathfinder, Acheson Industries Inc. (1965).
R. E. Franklin, Acta Crystallogr. 4 (1951) 253.
W. Ruland, “Chemistry and Physics of Carbon” edited by P. L. Walker Jr (Edward Arnold, New York, 1968) p. 1.
D. B. Fischbach, “Chemistry and Physics of Carbon”,Vol. 7, edited by P. L. Walker Jr (Marcel Dekker, New York, 1971) p. 1.
S. J. Paprocki, E. S. Hodge and C. B. Boyer, Proceedings of the 2nd United Nations, International Conference on the Peaceful Uses of Atomic Energy, New York, 1959.
C. B. Boyer, ASME, Paper 71-WA Prod-20, 15th July (1971).
W. Chard, M. Conaway and D. Niesz, “Petroleum Derived Carbons” in ACS Symposia Series No. 21, edited by M. L. Deviney and T. M. O'Grady, (ACS, Washington, 1976) Chap. 14.
H. K. Gilliam and M. P. Whittaker, Extended Abstracts of 11th Biennial Conference on Carbon, Gatlinburg, TE, USA, June 1973 (American Carbon Society) p. 211.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ragan, S., Marsh, H. Science and technology of graphite manufacture. J Mater Sci 18, 3161–3176 (1983). https://doi.org/10.1007/BF00544139
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00544139