Conclusions
The mechanisms of formation of a matrix-fibrillar fibre structure from melts of mixtures of thermodynamically compatible polymers on application of a mechanical field have been studied:
a mechanism which is inherent to thermodynamically incompatible polymers (for melts of potentially mutually soluble polymers which are nonuniform in composition);
the jet-fibre transition, which can be effected by a nucleation or spinodal mechanism in the amorphous separation of a homogeneous system, or as a crystallization separation on application of a mechanical field to the system.
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Literature cited
V. E. Vishnevskii, Yu. V. Pasechnik, M. Yakob, M. Yu. Kuchinka, M. V. Tsebrenko, and A. V. Yudin, Izv. Vyssh. Uchebn. Zaved., Ser. “Tekhnol. Leg. Promst.,” No. 6, 46–48 (1974).
B. T. Hayes, Chem. Eng. Progr., 65, No. 10, 50–54 (1969).
M. Yakob, Author's abstract of candidate's dissertation, KTILP, Kiev (1974).
O. V. Romankevich (Romankevič) and S. Ya. Frenkel', Acta Polym., 31, No. 5, 287–295 (1980).
A. A. Tager, The Physical Chemistry of Polymers [in Russian], Khimiya, Moscow (1978).
A. Ya. Malkin and A. E. Chalykh, Polymer Diffusion and Viscosity. Methods of Measurement [in Russian], Khimiya, Moscow (1979).
F. P. Price and P. T. Gilmor, J. Polym. Sci.: Polym. Symp., No. 63, 33–44 (1978).
Yu. S. Lipatov, Interfacial Phenomena in Polymers [in Russian], Naukova Dumka, Kiev (1980).
S. E. Zabello, O. V. Romankevich, A. V. Yudin, and S. N. Lugovaya, Khim. Volokna, No. 4, 8–10 (1974).
K. Dietrich and M. Versäumer, Faserf. Text., 26, No. 7, 347–352 (1975).
D. R. Paul, J. W. Barlow, and R. E. Bernstein, Polym. Eng. Sci., 18, No. 16, 1225–1235, (1978).
L. E. Bernatskaya and G. I. Kudryavtsev, in: Artificial Fibres, No. 3 [in Russian], Moscow (1952), pp. 88–92.
N. V. Mikhailov and V. O. Klessman, Kolloidn. Zh., 18, No. 4, 454–460 (1956).
A. Zyabitskii, Theoretical Bases of Fibre Spinning [in Russian], Khimiya, Moscow (1979), 504 pp.
F. D. Rumscheidt and S. V. Mason, J. Colloid. Sci., 16, No. 3, 238–261 (1961).
R. C. Cox, J. Fluid Mech., 37, No. 3, 601–623 (1969).
V. N. Kulesnev, Polymer Mixtures [in Russian], Khimiya, Moscow (1980), 303 pp.
S. Ya. Frenkel', V. G. Baranov, et al., in: Mechanism of Processes of Film-formation from Polymer Solutions and Dispersions [in Russian], Nauka, Moscow (1966), pp. 22–31.
S. Ya. Frenkel' and G. K. El'yashevich, in: Theory of Spinning Man-made Fibres [in Russian], Khimiya, Moscow (1975), pp. 91–111.
B. M. Ginzburg, E. T. Magdalev, V. N. Volosatov, R. G. Fedorova, and S. Ya. Frenkel', Vysokomol. Soed., Ser. A, 22, No. 10, 2200–2205 (1980).
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Translated from Khimicheskie Volokna, No. 2, pp. 51–53, March–April, 1985.
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Romankevich, O.V., Suprun, N.P. & Frenkel', S.Y. Matrix-fibrillar fibres from mixtures of thermodynamically compatible polymers. Fibre Chem 17, 165–169 (1985). https://doi.org/10.1007/BF00543479
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DOI: https://doi.org/10.1007/BF00543479