Abstract
This paper deals with the most common methods of interpretation of the thermally stimulated discharge (TSD) spectrum. TSD due to dipole disorientation, calculation of activation energies using initial rise method, graphical integration, and methods based on the variation of heating rates are described in some detail. It will be argued that calculation of activation energies from these methods strictly holds for relaxation of a single well-defined frequency. For a distributed relaxation, methods based on the variations of the heating rates are more appropriate, but certain difficulties may arise.
Similar content being viewed by others
References
S. M. Vaezi-Nejad, C. Juhasz and B. M. Z. Kama-Nuczaman, J. Mater. Sci. 27 (1992) 4305.
C. Bucci and R. Fiesch, Phys. Rev. Lett. 12 (1964) 16.
J. Van Turnhout, Polym. J. 2 (1971) 1973.
B. Gross, J. Electrochem. Soc. 115 (1968) 376.
J. Van Turnhout, “Thermally Stimulated Discharge of Polymer Electicets” (Elsevier, Amsterdam, 1975).
C. Lacabanne and D. Chatain, J. Polym. Sci. Polym. Phys. I 1 (1973) 2315.
N. G. McCrum, R. E. Read and G. Williams, “Anelastic and Dielectric Effects in Polymeric Solids” (Wiley, New York, 1967).
V. Daniels, “Dielectric Relaxation” (Academic Press, New York, 1967).
I. Thurzo and B. Barancok, J. Non-Cryst. Solids 18 (1975) 129.
A. Kivits and H. J. L. Hagebeuk, J. Luminescence 15 (1977) 1.
G. M. Sessler (Ed.), “Electicets”, Topics in Applied Physics Vol. 33, (Springer, Berlin, Heidelberg, 1980).
C. F. J. Garlick and A. F. Gibson, Proc. Phys. Soc. A60 (1948) 574.
C. Bucci, R. Fieschi and G. Guidi, Phys. Rev. 148 (1966) 816.
C. Laj and B. Berge, C.R. Acad. Sci. Paris B263 (1966) 380.
A. H. Booth, Can. J. Chem. 32 (1954) 214.
W. Bohun, Czech. J. Phys. 4 (1954) 91.
W. Hoogenstraaten, Philips Res. Rep. 13 (1958) 515.
I. Grossweiner, J. Appl. Phys. 14 (1953) 1306.
A. Halperin and A. A. Branes, Phys. Rev. 117 (1960) 408.
R. Chen, J. Appl. Phys. 40 (1969) 570.
Idem, J. Electrochem. Soc. 116 (1969) 1254.
C. Christodevlides, J. Phys. D. 18 (1985) 1501.
J. Vanderschveren and J. Gasiot, in “Thermally Stimulated Relaxation in Solids”, edited by P. Braunlich, “Topics in Applied Physics”, Vol. 37 (Springer-Verlag, Berlin, Heidelberg, New York, 1979) Ch. 4.
H. J. Wincle, J. Appl. Phys. 42 (1971) 4724.
A. Kessler and J. E. Caffyn, J. Phys. C 5 (1972) 1134.
S. C. Agarwal, Phys. Rev. B10 (1974) 4340.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vaezi-Nejad, S.M., Kamarulzaman, B.M.Z. & Juhasz, C. Analysis of thermally stimulated discharge data on amorphous semiconductors. J Mater Sci 27, 4311–4315 (1992). https://doi.org/10.1007/BF00541558
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00541558