Abstract
A simple surface treatment is found to improve mechanical strength of corundum crystals. The surface treatment is as follows: the titanium mono-oxide layer, 0.1 μm, thick is deposited onto the polished surface of the corundum crystals and the crystals are then fired at 1200 to 1300° C for a few hours in air. The treatment improves the mechanical strength of the corundum crystal surface. The surface microhardness increases by nearly × 2 and the mean wear resistance against the iron plate increases by several times. The surface hardening mechanism is discussed in relation to the diffusion of titanium ion into the corundum crystals.
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Nagai, T., Wasa, K. & Hayakawa, S. Surface hardening of ruby and sapphire. J Mater Sci 11, 1509–1512 (1976). https://doi.org/10.1007/BF00540885
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DOI: https://doi.org/10.1007/BF00540885