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Wetting of silicon nitride by alkaline-doped MgSiO3

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Abstract

The wetting behaviour of Si3N4 by alkaline-doped MgSiO3 was investigated by the sessile drop method. It is shown that the alkaline oxide additions improve the wetting of MgSiO3 on Si3N4. The hot-pressing of Si3N4 is controlled by a liquid phase sintering process where the dissolution of Si3N4 in silicate glass promotes good wetting and a well bonded interface by lowering the liquid-solid interfacial energy. Controlling total alkaline impurity level between 50 and 100 ppm is suggested for an optimal strength performance.

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References

  1. S. Wild, P. Grieveson, K. H. Jack and M. J. Latimer, in “Special Ceramics 5” (edited by P. Popper) (British Ceramics Association, 1972) p. 377.

  2. Ram Kossowsky, J. Mater. Sci. 8 (1973) 1603.

    Google Scholar 

  3. F. F. Lange and G. R. Terwilliger, Final Report, Contract N00019-17-C-0107, Dept. of the Navy.

  4. A. G. Evans and J. V. Sharp, J. Mater. Sci. 6 (1971) 1292.

    Google Scholar 

  5. T. J. Whalen and M. Humenik, Jun, in “Sintering and Related Phenomena” (edited by G. C. Kuczynski, N. A. Hooton and C. F. Gibbon) (Gordon and Breach, New York, 1967) p. 715.

    Google Scholar 

  6. See for example in W. D. Kingery, “Introduction to Ceramics” (John Wiley, New York, 1960).

    Google Scholar 

  7. E. M. Levine, C. R. Robbins and H. F. McMurdie, “Phase Diagrams for Ceramists”, (American Ceramic Society, 1964) pp. 209, 151, 165.

  8. R. Rosen, J. Bersan and G. Urbain, Rev. Hautes Temper. et. Refract. 1 (1964) 159.

    Google Scholar 

  9. Ram Kossowsky, J. Amer. Ceram. Soc. 56 (1973) 531.

    Google Scholar 

  10. Idem, in Proceedings, “Second Army Materials Conference”, Hyannis, MA, November 1973.

  11. Ram Kossowsky, D. G. Miller and E. S. Diaz, “Tensile and Creep Properties of Hot-Pressed Si3N4” to be published.

  12. J. L. Iskoe and F. F. Lange, paper presented at the Spring meeting, Basic Science Div., Amer. Ceram. Soc., Pittsburgh, May 1973 (paper 42-BC-73F).

    Google Scholar 

  13. R. F. Coe, R. J. Lumby and M. F. Pawson, in “Special Ceramics 5” (edited by P. Popper) (British Ceramics Association, 1972) p. 361.

  14. C. A. Andersson, Westinghouse Research Laboratories, private communication.

  15. W. A. Zisman, in “Contact Angle, Wettability and Adhesion” (edited by R. F. Gould) (Amer. Chem. Soc., 1964) p. 3.

  16. S. K. Rhee, J. Amer. Ceram. Soc. 7 (1971) 332.

    Google Scholar 

  17. W. D. Kingery, “Introduction to Ceramics” (John Wiley, New York, 1960) p. 206.

    Google Scholar 

  18. A. Dupre, “Theorie Mechanique de la Chaleur” (Gauthier-Villars, Paris, 1964) p. 369.

    Google Scholar 

  19. A. L. Prill, H. W. Hayden and J. H. Brophy, Tram. Met. Soc. AIME 233 (1965) 960.

    Google Scholar 

  20. W. D. Kingery, J. Appl. Phys. 30 (1959) 301.

    Google Scholar 

  21. G. E. Gazza, paper presented at the Spring meeting, Basic Science Div., Amer. Ceram. Soc., Pittsburgh, September 1973 (paper 5-BC-73F).

    Google Scholar 

  22. Idem, Army Materials and Mechanics Research Center, private communication.

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Kossowsky, R. Wetting of silicon nitride by alkaline-doped MgSiO3 . J Mater Sci 9, 2025–2033 (1974). https://doi.org/10.1007/BF00540552

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