Abstract
The permanent equilibrium transfer of the toluene-sulfonate group to arylate ions in 80 vol. % aqueous DMSO (μ = 0.1 KCl) at 25°C has been studied. The full kinetic and thermodynamic analysis has shown that the reaction is based on a matched symmetrical mechanism. The factors responsible for an increase in the reactivity of the arylate onions, when the reaction is carried out in 80% aqueous DMSO instead of in water, is discussed.
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 6, pp. 319–322, November–December, 1994.
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Simanenko, Y.S., Zubareva, T.M., Savelova, V.A. et al. Permanent transfer of the acyl group of aryltoluenesulfonates to arylate ions in aqueous demethylsulfoxides. Theor Exp Chem 30, 278–281 (1995). https://doi.org/10.1007/BF00538123
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DOI: https://doi.org/10.1007/BF00538123