Skip to main content
SpringerLink
Log in

Cathodic initiation of reactions of macromolecule formation and degradation

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

Research in the field of cathodic initiation of macromolecule polymerization and degradation is reviewed in this article. A mechanism is proposed for electrochemical initiation of anionic polymerization of oligoesteracrylates, as well as an accumulative mechanism of electrochemical reductive degradation (ECRD) of cross-linked polymers. Indirect initiation of ECRD of carbochain polymers through a dissociative mechanism is examined. Problems and perspectives are set forth for the development of electrochemical initiation of processes of polymerization and degradation of macromolecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Baizer and H. Lund (eds.), Organic Electrochemistry, Marcel Dekker, New York (1983).

    Google Scholar 

  2. A. P. Tomilov and G. F. Shaidulina, Itogi Nauki Tekh., Ser. Élektrokhim. (VINITI, Moscow), 39, 4–52 (1993).

    Google Scholar 

  3. Yu. P. Kitaev, T. V. Tropol'skaya, and G. K. Budnikov, Intermediate Species in Electrochemical Reactions [in Russian], Nauka, Moscow (1982).

    Google Scholar 

  4. O. N. Efimov and V. V. Strelets, Usp. Khim., 57, No. 2, 228–253 (1988).

    Google Scholar 

  5. A. P. Tomilov, Élektrokhimiya, 30, No. 6, 725–738 (1994).

    Google Scholar 

  6. V. D. Pokhodenko, V. G. Koshechko, V. E. Titov, and D. V. Sednev, Teor. Éksp. Khim., 28, No. 2, 97–114 (1992).

    Google Scholar 

  7. V. D. Pokhodenko, V. D. Koshechko, V. E. Titov, et al., in: 40th ICE Meeting, Kyoto, September 17–22, 1989 (Extended Abstracts), Kyoto (1989), Vol. 2, p. 905.

  8. V. G. Koshechko, V. E. Titov, D. V. Sednev, and V. D. Pokhodenko, in: New Developments in the Electrochemistry of Organic Compounds, 1990 (12th All-Union Conference “Electrochemistry of Organic Compounds” [in Russian], Karaganda, September, 1990, pp. 93–94.

  9. V. D. Pokhodenko, V. G. Koshechko, V. E. Titov, and V. A. Lopushanskaya, in: New Developments in the Electrochemistry of Organic Compounds [in Russian], IÉRAN, Moscow, Tambov (1994), pp. 60–61.

    Google Scholar 

  10. G. S. Shapoval and A. V. Gorodyskii, Usp. Khim., 42, No. 5, 854–880 (1973).

    Google Scholar 

  11. G. S. Shapoval and T. E. Lipatova, Electrochemical Initiation of Polymerization [in Russian], Naukova Dumka, Kiev (1977).

    Google Scholar 

  12. G. S. Shapoval, Ion Radicals in Electrode Processes [in Russian], Nauka, Moscow (1983), pp. 286–317.

    Google Scholar 

  13. G. S. Shapoval, in: Electrosynthesis; Electrode Reactions with the Participation of Organic Compounds [in Russian], Nauka, Moscow (1990), pp. 151–184.

    Google Scholar 

  14. A. A. Pud and G. S. Shapoval, Élektrokhimiya, 28, No. 4, 654–668 (1992).

    Google Scholar 

  15. G. S. Shapoval, in: Abstracts of International Symposium on Novel Aspects of Electrogenerated Active Species and Their Reactions, Okayama (Japan), September 24–25, 1994, pp. 59–60.

  16. C. L. Wilson, Rec. Chem. Prog., 10, No. 1, 25–30 (1949).

    Google Scholar 

  17. M. Kolthoff and L. L. Ferstanding, J. Polym. Sci., 6, No. 5, 563–574 (1951).

    Google Scholar 

  18. G. S. Shapoval and V. I. Shapoval, Sint. Fiz.-Khim. Polim. (Naukova Dumka, Kiev), pp. 121–133 (1964).

    Google Scholar 

  19. N. Yamazaki, Adv. Polym. Sci., 6, No. 3, 377–400 (1969).

    Google Scholar 

  20. G. S. Shapoval, Ukr. Khim. Zh., 33, No. 9, 946–949 (1967).

    Google Scholar 

  21. V. D. Bezuglyi and T. A. Alekseeva, in: Electrosynthesis and Bioelectrochemistry [in Russian], Nauka, Moscow (1975), pp. 156–198.

    Google Scholar 

  22. J. W. Breitenbach, O. F. Olaj, and F. Sommer, Adv. Polym. Sci., 9, No. 1, 47–68 (1972).

    Google Scholar 

  23. H. L. Friedlander, in: Encyclopedia of Polymer Science and Technology, Wiley Interscience, New York (1966), Vol. 5, pp. 629–641.

    Google Scholar 

  24. G. Hoijtink and J. Van Schooten, Rec. Trav. Chim., 71, No. 8, 1089–1093 (1952).

    Google Scholar 

  25. A. P. Tomilov, S. G. Mairanovskii, M. Ya. Floshin, and V. A. Smirnov, in: Electrochemistry of Organic Compounds [in Russian], Khimiya, Leningrad (1968), p. 162.

    Google Scholar 

  26. R. V. Lindsey and M. L. Peterson, J. Am. Chem. Soc., 81, No. 9, 2073–2074 (1959).

    Google Scholar 

  27. G. N. Freidlin and E. P. Kovsman, Itogi Nauki Tekh., Ser. Élektrokhim. (VINITI, Moscow), 39, 206–222 (1993).

    Google Scholar 

  28. E. M. Skobets and G. S. Shapoval, Dokl. Akad. Nauk SSSR, 29, No. 3, 302–306 (1962).

    Google Scholar 

  29. G. S. Shapoval, A. P. Kanareitseva, and E. M. Skobets, Dokl. Akad. Nauk Ukr. SSR, Ser. B, No. 10, 926–928 (1971).

    Google Scholar 

  30. B. L. Funt and S. N. Bhadani, J. Polym. Sci. A, 3, No. 12, 4149–4199 (1965).

    Google Scholar 

  31. N. S. Tsvetkov, Vysokomol. Soedin., 3, No. 4, 549–552 (1961).

    Google Scholar 

  32. G. S. Shapoval, E. M. Skobets, and A. P. Kanareitseva, in: New Developments in the Electrochemistry of Organic Compounds [in Russian], Zinatne, Riga (1973), pp. 68–69.

    Google Scholar 

  33. G. S. Shapoval, M. Ya. Fioshin, and E. M. Skobets, Élektrokhimiya, 10, No. 2, 267–269 (1974).

    Google Scholar 

  34. L. G. Kolzunova and N. Ya. Kovarskii, Polymeric Coatings on Metals [in Russian], Nauka, Moscow (1976).

    Google Scholar 

  35. K. A. Makarov, Ya. D. Zytner, and V. A. Myshlenikava, Electrochemical Polymeric Coatings [in Russian], Khimiya, Leningrad (1982).

    Google Scholar 

  36. E. P. Koval'chuk, E. A. Aksiment'eva, and A. P. Tomilov, Electrosynthesis of Polymers on Metal Surfaces [in Russian], Khimiya, Moscow (1991).

    Google Scholar 

  37. L. G. Kolzunova, I. Yu. Kalugina, and M. Ya. Kovarskii, in: New Developments in the Electrochemistry of Organic Compounds [in Russian], IÉRAN, Moscow, Tambov (1994), pp. 127–128.

    Google Scholar 

  38. Ya. D. Zytner and K. Ya. Makarov, in: New Developments in the Electrochemistry of Organic Compounds [in Russian], IÉRAN, Moscow, Tambov (1994), pp. 126–127.

    Google Scholar 

  39. B. Scrosati, Prog. Solid State Chem., 18, No. 1, 1–77 (1988).

    Google Scholar 

  40. F. Gran'e, Usp. Fiz. Nauk, 157, No. 3, 513–527 (1989).

    Google Scholar 

  41. N. F. Guba, O. A. Gaiduk, and V. D. Pokhodenko, Teor. Éksp. Khim., 29, No. 2, 143–147 (1993).

    Google Scholar 

  42. A. A. Pud, “Cathodic initiation of polymer formation and degradation reactions,” Author's Abstract of Candidate's Dissertation, Kiev (1985).

  43. B. L. Funt, Macromol. Rev., 1, No. 1, 35–56 (1966).

    Google Scholar 

  44. G. S. Shapoval, T. E. Lipatova, and E. S. Shevchuk, Vysokomol. Soedin. B, 19, No. 5, 358–359 (1977).

    Google Scholar 

  45. G. S. Shapoval, T. E. Lipatova, and E. S. Shevchuk, Ukr. Khim. Zh., 43, No. 1, 123–128 (1977).

    Google Scholar 

  46. G. S. Shapoval, J. Macromol. Sci. Chem. A, 17, No. 3, 453–466 (1982).

    Google Scholar 

  47. G. S. Shapoval, E. M. Skobets, and A. P. Kanareitseva, Ukr. Khim. Zh., 38, No. 8, 805–809 (1972).

    Google Scholar 

  48. T. E. Lipatova, G. S. Shapoval, et al., J. Polym. Sci., Polym. Symp., 1, No. 42, 1–23 (1973).

    Google Scholar 

  49. T. E. Lipatova, G. S. Shapoval, and E. S. Shevchuk, J. Macromol. Sci. Chem. A, 5, No. 2, 345–356 (1971).

    Google Scholar 

  50. G. S. Shapoval, E. M. Skobets, A. P. Kanareitseva, and M. Ya. Fioshin, Élektrokhimiya, 9, No. 12, 1876–1878 (1973).

    Google Scholar 

  51. G. S. Shapoval, T. E. Lipatova, and E. S. Shevchuk, Sint. Fiz.-Khim. Polim., No. 17, 3–10 (1975).

    Google Scholar 

  52. G. S. Shapoval, E. S. Shevchuk, and Yu. G. Dubovik, in: Heterogeneous Polymeric Materials [in Russian], Naukova Dumka, Kiev (1973), pp. 129–136.

    Google Scholar 

  53. G. S. Shapoval, A. P. Tomilov, and A. A. Pud, Élektrokhimiya, 18, No. 12, 1665–1668 (1982).

    Google Scholar 

  54. G. S. Shapoval, A. A. Pud, and O. V. Aksenova, Teor. Éksp. Khim., 19, No. 2, 230–235 (1983).

    Google Scholar 

  55. O. M. Shepel' and G. S. Shapoval, Teor. Éksp. Khim., 24, No. 4, 492–495 (1988).

    Google Scholar 

  56. G. S. Shapoval, A. V. Gorodyskii, A. P. Tomilov, and A. A. Pud, Dokl. Akad. Nauk SSSR, 263, No. 5, 1179–1182 (1982).

    Google Scholar 

  57. A. A. Pud, Synth. Met., 66, No. 1, 1–18 (1994).

    Google Scholar 

  58. A. A. Pud, G. S. Shapoval, A. P. Tomilov, and T. S. Yatsimirskaya, Teor. Éksp. Khim., 20, No. 5, 584–589 (1984).

    Google Scholar 

  59. G. S. Shapoval, T. É. Lipatova, and E. S. Shevchuk, Ukr. Khim. Zh., 43, No. 11, 1203–1207 (1977).

    Google Scholar 

  60. G. S. Shapoval, A. A. Pud, and A. P. Tomilov, Dokl. Akad. Nauk SSSR, 283, 434–437 (1985).

    Google Scholar 

  61. G. S. Shapoval, A. A. Pud, V. P. Kukhar', and A. P. Tomilov, Dokl. Akad. Nauk SSSR, 305, No. 2, 335–339 (1989).

    Google Scholar 

  62. G. S. Shapoval, A. A. Pud, A. P. Tomilov, and K. V. Batsalova, in: Summaries of Papers from 7th All-Union Conference on Electrochemistry [in Russian], Chernovtsy, September 10–14, 1988, Vol. 3, p. 197.

  63. G. S. Shapoval and A. A. Korzhenko, in: Summaries of Papers from All-Union Seminar “Modern Methods for the Investigation of Corrosion Damage” [in Russian], Sevastopol, October 6–11, 1991; published by Izhevsk, Sevastopol (1991), pp. 142–143.

  64. A. A. Pud and G. S. Shapoval, in: 10th International Congress on Metal Corrosion, Madras, New Delhi, etc., 1987, Vol. 2, pp. 1101–1102.

    Google Scholar 

  65. G. S. Shapoval, B. A. Sternik, A. P. Tomilov, and A. A. Pud, Élektrokhimiya, 18, No. 8, 1028–1032 (1982).

    Google Scholar 

  66. G. S. Shapoval, A. P. Tomilov, K. V. Batsalova, and A. A. Pud, Vysokomol. Soedin. A, 23, No. 7, 1424–1430 (1987).

    Google Scholar 

  67. G. S. Shapoval, Yu. V. Kontsur, A. V. Bukhtiarov, et al., Élektrokhimiya, 30, No. 5, 686–689 (1994).

    Google Scholar 

  68. A. A. Pud, Polym. Degrad. Stab., 30, 181–185 (1990).

    Google Scholar 

  69. G. S. Shapoval, A. A. Pud, P. V. Zamotaev, and A. A. Kachan, Vysokomol. Soedin. A, 23, No. 11, 2161–2164 (1987).

    Google Scholar 

  70. G. S. Shapoval, Yu. V. Fateev, O. É. Mikulina, et al., Zashch. Met., 28, No. 2, 341–344 (1992).

    Google Scholar 

  71. A. A. Pud, G. S. Shapoval, V. K. Skubin, et al., Teor. Éksp. Khim., 25, No. 6, 711–715 (1989).

    Google Scholar 

  72. A. A. Pud, G. S. Shapoval, and O. É. Mikulina, Prib. Tekh. Éksp., No. 4, 213–215 (1991).

    Google Scholar 

  73. Z. Osawa and Y. Uchida, J. Polym. Sci., 20, No. 10, 2259–2266 (1982).

    Google Scholar 

  74. G. S. Shapoval and I. V. Kontsur, in: Abstracts of 9th Bratislava Conference “Modification of Thermoplastic Polymers,” June 14–18, 1993, Bratislava, pp. 124–125.

  75. C. J. Timmons and E. S. Stern (eds.), Gillam and Stern's Introduction to Electronic Absorption Spectroscopy in Organic Chemistry, 3rd ed., St. Martin, New York (1971).

    Google Scholar 

  76. S. E. Evsyukov, Yu. P. Kudryavtsev, and Yu. V. Korshak, Usp. Khim., 69, No. 4, 764–798 (1991).

    Google Scholar 

  77. B. I. Imanakunov, T. P. Kim, and T. T. Baidinov, Reactions of Formamide and Dimethylformamide with Inorganic Salts [in Russian], ILIM, Frunze (1986).

    Google Scholar 

  78. A. A. Pud, in: Abstracts of 44th ISE Meeting, Berlin, September 5–10, 1993, 0∶1.7.3 (1993).

  79. S. Pous, Electrochem. Acta, 27, 1161–1167 (1982).

    Google Scholar 

  80. A. A. Pud, G. S. Shapoval, A. P. Tomilov, and O. É. Mikulina, Élektrokhimiya, 28, No. 6, 880–886 (1992).

    Google Scholar 

  81. G. S. Shapoval, Summaries of Papers from 7th Republic Conference on Macromolecular Compounds [in Russian], Rubezhnoe, October 10–13, 1991, pp. 157–158.

  82. A. A. Pud, L. L. Gervits, G. S. Shapoval, and O. É. Mikulina, Élektrokhimiya, 28, No. 5, 825 (1992).

    Google Scholar 

  83. O. E. Mikulina, G. S. Shapoval, and A. A. Pud, in: Abstracts of 9th Bratislava Conference “Modification of Thermoplastic Polymers,” June 14–18, 1993, Bratislava, pp. 109–110.

  84. A. A. Pud, G. S. Shapoval, O. E. Mikulina, and L. L. Gervits, in: Abstracts of Papers from 44th ISE Meeting, Berlin, September 5–10, 1993, p: 1.4.9 (1993).

Download references

Author information

Authors and Affiliations

  1. Institute of Bioorganic Chemistry and Petroleum Chemistry, National Academy of Sciences of the Ukraine, 1Murmanskaya Street, 252660, Kiev-94, Ukraine

    G. S. Shapoval

Authors
  1. G. S. Shapoval
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 6, pp. 307–318, November–December, 1994.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shapoval, G.S. Cathodic initiation of reactions of macromolecule formation and degradation. Theor Exp Chem 30, 265–277 (1995). https://doi.org/10.1007/BF00538122

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00538122

Keywords

Search

Navigation