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Conformationally rigid hexaazamacrocyclic complexes of nickel(II) as selective hydrosulfate receptors in comparison with dihydrophosphate

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Abstract

It was shown on the example of two-point interaction of hydrosulfate and dihydrophosphate with hexaazamacrocyclic complexes of nickel(II) that the presence of nitrogen atoms in the ligand molecule of conformationally rigid chelate rings with an equatorial unshared pair of electrons leads to a decrease in the anionbonding efficiency; however, it enhances the differentiating effect between them in comparison with the receptor in which the nitrogen atom is included in a conformationally flexible chelate ring.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauki Prospekt, 252039, Kiev, Ukraine

    L. V. Tsymbal & Ya. D. Lampeka

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  1. L. V. Tsymbal
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  2. Ya. D. Lampeka
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 5, pp. 298–302, September–October, 1994.

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Tsymbal, L.V., Lampeka, Y.D. Conformationally rigid hexaazamacrocyclic complexes of nickel(II) as selective hydrosulfate receptors in comparison with dihydrophosphate. Theor Exp Chem 30, 259–263 (1995). https://doi.org/10.1007/BF00536701

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  • DOI: https://doi.org/10.1007/BF00536701

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