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Kinetic model for the photoreactions of d0-oxo-complexes applied to SiO2

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Abstract

Based on literature data a kinetic model has been devised for the photoreactions of d0-oxo-complexes (Ti4+, V5+, Cr6+, Mo6+, and W6+) with H2, alkanes, CO and alkenes, fixed on supports. Equations have been obtained for the rate and quantum yields of the reactions and photosphorescence.

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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 5, pp. 268–271, September–October, 1994.

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Tret'yakov, V.P. Kinetic model for the photoreactions of d0-oxo-complexes applied to SiO2 . Theor Exp Chem 30, 230–232 (1995). https://doi.org/10.1007/BF00536695

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  • DOI: https://doi.org/10.1007/BF00536695

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