Abstract
Based on literature data a kinetic model has been devised for the photoreactions of d0-oxo-complexes (Ti4+, V5+, Cr6+, Mo6+, and W6+) with H2, alkanes, CO and alkenes, fixed on supports. Equations have been obtained for the rate and quantum yields of the reactions and photosphorescence.
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References
E. Liver, Electron Spectroscopy of Inorganic Compounds Part 1 [Russian translation], Mir, Moscow (1987).
V. B. Kazanskii, Kinet. Katal., 24, No. 6, 1338–1346 (1983).
S. L. Kaliaguine, B. N. Shelimov, and V. B. Kazanskii, J. CataL, 55, No. 3, 384–393 (1978).
M. Anpo, M. Kondo, S. Coluccia, et al., J. Am. Chem. Soc., 111, No. 24, 8791–8799 (1989).
V. P. Tret'yakov, Khim. Vys. Energ., 28, No. 2, 139–144 (1994).
A. A. Konnov, A. N. Pershin, B. N. Shelimov, and V. B. Kazanskii, Kinet. Katal., 24, No. 1, 155–160 (1983).
M. Anpo, I. Tanahashi, and Y. Kubokawa, J. Phys. Chem., 86, No. 1, 1–3 (1982).
M. Anpo, I. Tanahashi, and Y. Kubokawa, J. Phys. Chem., 84, No. 25, 3440–3443 (1980).
S. A. Surin, A. D. Shukov, B. N. Shelimov, and V. B. Kazanskii, Khim. Vys. Energ., 11, No. 2, 147–151 (1977).
M. Anpo, M. Nakaya, S. Kodama, et al., J. Phys. Chem., 90, No. 8, 1633–1636 (1986).
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 5, pp. 268–271, September–October, 1994.
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Tret'yakov, V.P. Kinetic model for the photoreactions of d0-oxo-complexes applied to SiO2 . Theor Exp Chem 30, 230–232 (1995). https://doi.org/10.1007/BF00536695
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DOI: https://doi.org/10.1007/BF00536695