Skip to main content
Log in

Molecular translational-motion correlation time in liquid benzene

  • Brief Communications
  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

A model-free method is used for determining dipole-dipole nuclear-spin interaction correlation times for liquids from the spin-lattice relaxation times on the basis of the molecular shape, the spin positions in the molecules, and the spin distribution in the liquid. An estimate has been made of the proton relative-motion correlation time for liquid benzene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. T. N. Khazanovich and V. Yu. Zitserman, “On external dipolar relaxation in two-spin systems,” Mol. Phys., 21, No. 1, 65–82 (1971).

    Google Scholar 

  2. A. H. Narten, “X-ray diffraction pattern and models of liquid benzene,” J. Chem. Phys., 67, No. 5, 2102–2108 (1977).

    Google Scholar 

  3. B. P. Nikol'skii (ed.), Chemist's Handbook [in Russian], Goskhimizdat, Moscow-Leningrad (1963), Vol. 1.

    Google Scholar 

  4. M. V. Vol'kenshtein, Molecular Structures and Physical Properties [in Russian], Izd. AN SSSR, Moscow (1955).

    Google Scholar 

  5. N. K. Gaisin, “Intramolecular and intermolecular contributions to proton spin-lattice relaxation in benzene and cyclohexane,” Izv. VUZ. Fiz., No. 3, 116–121 (1971).

    Google Scholar 

  6. C. S. Hsu and D. Chandler, “RISM calculation on the structure of liquid acetonitrile,” Mol. Phys., 36, No. 1, 215–224 (1978).

    Google Scholar 

  7. L.-P. Hwang, “Intermolecular nuclear relaxation and RISM pair-correlation function in liquids,” ibid., 51, No. 5, 1235–1241 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 4, pp. 504–506, July–August 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gaisin, N.K., Khusainov, K.Z. Molecular translational-motion correlation time in liquid benzene. Theor Exp Chem 23, 473–475 (1988). https://doi.org/10.1007/BF00536373

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00536373

Keywords

Navigation