Skip to main content
SpringerLink
Log in

Mass-spectrometric study of methoxysilyl group hydrolysis on silica

  • Brief Communications
  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

Thermally programmed desorption and isotopic labeling with oxygen 18 have been used to examine the hydrolysis mechanisms for methoxy groups grafted to serosil. The isotope effect is used in a proposed nucleophilic reaction mechanism.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. V. A. Tertykh, “Features of alcohol chemisorption on silica,” Adsorbts. Adsorb., No. 11, 3–11 (1983).

    Google Scholar 

  2. V. V. Brei and A. A. Chuiko, “A mass-spectrometric study of methoxysilyl-group hydrolysis kinetics for silica under conditions of linearly rising temperature,” Teor. Eksp. Khim., 21, No. 5, 634–637 (1985).

    Google Scholar 

  3. M. Hino and T. Sato, “Infrared absorption spectra of silica gel H2 16O, D2 16O, and H2 18O systems,” Bull. Chem. Soc. Jpn., 44, No. 1, 33–37 (1971).

    Google Scholar 

  4. L. Melander, Isotope Effects in Reaction Rates [Russian translation], Mir, Moscow (1964).

    Google Scholar 

  5. D. Eisenberg and W. Kauzman, The Structure and Properties of Water [Russian translation], Gidrometeoizdat, Leningrad (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    V. V. Brei, V. A. Pokrovskii & A. A. Chuiko

  2. Institute of Surface Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    V. V. Brei, V. A. Pokrovskii & A. A. Chuiko

Authors
  1. V. V. Brei
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Pokrovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Chuiko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 4, pp. 501–504, July–August 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Brei, V.V., Pokrovskii, V.A. & Chuiko, A.A. Mass-spectrometric study of methoxysilyl group hydrolysis on silica. Theor Exp Chem 23, 471–473 (1988). https://doi.org/10.1007/BF00536372

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00536372

Keywords

Search

Navigation