Abstract
A mechanism has been proposed for the reaction of CO + NO + (O2) on palladium catalysts and the elementary stages of the reaction have been subjected to thermodynamic analysis. A kinetic model of the reaction has been constructed. The model of the reaction CO + NO has been analyzed in comparison with the reaction CO + O2; the existence of a multiplicity of stationary states and critical transitions in the system CO + NO has been demonstrated. Numerical calculation has explained the accelerating influence of oxygen and the inhibiting influence of CO on the rate of the reaction CO + NO, observed experimentally.
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 4, pp. 484–489, July–August 1987.
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Pyatnitskii, Y.I., Martsenyuk-Kukharuk, M.G., Orlik, S.N. et al. Mechanism of the reaction of CO with NO on palladium catalysts. Theor Exp Chem 23, 454–458 (1988). https://doi.org/10.1007/BF00536368
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DOI: https://doi.org/10.1007/BF00536368