Abstract
The photochemical reactions of phthalimide, N-benzylphthalimide, 3-and 4-aminophthalimide in the presence of halomethanes have been studied. The end products of the reaction were identified. It was found that phthalimides do not undergo a chemical reaction under the action of light, and their transformations are determined by a reaction with the active products of the photodissociation of tetrachloromethane in the presence of oxygen.
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Literature cited
E. Inoue, H. Kokado, I. Shimizu, and Y. Tarahashi, “Possibility of creation of photosystems with:carbon tetrachloride,” J. Chem. Soc. Jpn. Chem. Sec., 74, No. 7, 1483–1484 (1971).
N. A. Borisevich, V. V. Gruzinskii, I. I. Kalosha, and V. A. Tolkachev, “Generation on solutions of certain complex molecules,” Zh. Prikl. Spektr., 11, No. 1, 173–174 (1969).
J. Calvert and J. Pitts, Photochemistry [Russian translation], Mir, Moscow (1968).
E. S. Weissberger, E. S. Proskauer, J. Riddik, and E. Toops, Organic Solvents [Russian translation], IL, Moscow (1958).
N. G. Vakhshiev, “Universal intermolecular interactions and their influence on the position of electronic spectra of molecules in two-component solutions,” Opt. Spektr., 13, No. 2, 192–199 (1962).
G. Meier, Analysis and Determination of Organic Compounds [Russian translation], Goskhimizdat, Leningrad (1937).
G. A. Korsunovskii, “Characteristic features of photochemical reaction of crystalline violet carbinol in CCl4,” Zh. Fiz. Khim., 42, No. 1, 264–266 (1968).
A. Matsuda, H. Kokado, and E. Inoue, “The photocurrent in the system of CCl4 and hydrogen donor via photolysis of CCl4,” J. Chem. Soc. Jpn. Pure Chem. Sec., 92, No. 1, 47–50 (1971).
N. M. Émanuél' and D. G. Knorre, Course on Chemical Kinetics [in Russian], Vysshaya Shkola, Moscow (1969).
W. R. Ware and C. Lewis, “Wavelength effects in fluorescence quenching. Aromatic hydrocarbons quenched by carbon tetrachloride,” J. Chem. Phys., 57, No. 8, 3546–3557 (1972).
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 4, pp. 480–484, July–August 1987.
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Gurinovich, V.V., Gruzinskii, V.V. & Tsvirko, M.P. Spectroscopic determination of photostimulated reactions in halomethane solutions of phthalimide and its derivatives. Theor Exp Chem 23, 450–454 (1988). https://doi.org/10.1007/BF00536367
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DOI: https://doi.org/10.1007/BF00536367