Theoretical and Experimental Chemistry

, Volume 30, Issue 1, pp 43–46 | Cite as

Transformations of a polynuclear silver(I) complex with a ligand containing phosphorus and sulfur under the influence of a strong electric field and fast-atom bombardment

  • G. G. Talanova
  • K. B. Yatsimirskii
  • V. G. Golovatyi
  • V. P. Shabel'nikov
  • P. N. Grabovyl
Article
  • 22 Downloads

Abstract

Gas-phase transformations of a new polynuclear silver(I) complex Ag3 (L-H)2NO3 (where L is Ph2P(S)CH2P(S)Ph2) under the influence of a strong electric field and fast-atom bombardment have been studied using FD and FAB mass spectrometry. Fragmentation of the complex in both cases was shown to proceed in the same way. Differences in the FD and FAB mass spectra of this complex were due to secondary hydrolytic and redox reactions of the ligand.

Keywords

Sulfur Phosphorus Mass Spectrometry Mass Spectrum Redox Reaction 

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Copyright information

© Plenum Publishing Corporation 1994

Authors and Affiliations

  • G. G. Talanova
    • 1
  • K. B. Yatsimirskii
    • 1
  • V. G. Golovatyi
    • 1
  • V. P. Shabel'nikov
    • 1
  • P. N. Grabovyl
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryUkraine Academy of SciencesKiev

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