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Effect of the chemical nature of the second component on the electronic state and adsorption capacity of rhodium on supported catalysts

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Abstract

XPS, Mossbauer spectroscopy, IRS, and electron microscopy were used to study the electronic state and adsorption capacity of rhodium in supported bimetallic catalysts. The introduction of a second component (M') into Rh/Al2O3 alters the oxidation state of rhodium, which, in turn, affects the strength of the adsorption bond in the Rh-CO complex.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Physical Chemistry Institute, National Academy of Sciences of Ukraine, Kiev

    S. B. Vorgin, A. I. Tripol'skii, N. V. Pavlenko & G. D. Zakumbaeva

  2. D. V. Sokol'skii Institute of Organic Catalysis and Electrochemistry, Academy of Sciences of Kazakhstan, Alma-Ata

    S. B. Vorgin, A. I. Tripol'skii, N. V. Pavlenko & G. D. Zakumbaeva

Authors
  1. S. B. Vorgin
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  2. A. I. Tripol'skii
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  3. N. V. Pavlenko
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  4. G. D. Zakumbaeva
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 1, pp. 39–44, January–February, 1994.

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Vorgin, S.B., Tripol'skii, A.I., Pavlenko, N.V. et al. Effect of the chemical nature of the second component on the electronic state and adsorption capacity of rhodium on supported catalysts. Theor Exp Chem 30, 34–38 (1994). https://doi.org/10.1007/BF00535920

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  • DOI: https://doi.org/10.1007/BF00535920

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