Abstract
Products and intermediate compounds formed in oscillating chemical reactions of oxidation of copper and nickel tetraazamacrocyclic complexes were studied by the method of desorption field mass spectrometry. It was shown that a cascadelike oxidation of the macrocyclic ligand takes place and its hydrolysis with rupture of the macrocyclic ring at the azomethine bonds. Products of bromination of oxygen- and nitrogen-containing compounds, participants in the reactions, were discovered.
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 2, pp. 221–225, March–April, 1987.
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Yatsimirskii, K.B., Kol'chinskii, A.G., Zakrevskaya, L.N. et al. Mass spectrometric study of products and intermediate compounds in oscillating chemical reactions of oxidation of macrocyclic copper and nickel complexes by a bromate. Theor Exp Chem 23, 207–211 (1987). https://doi.org/10.1007/BF00534585
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DOI: https://doi.org/10.1007/BF00534585