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Solvation of tetraphenylphosphonium dicyanamide

Theoretical and Experimental Chemistry volume 24, pages 351–355 (1988)Cite this article

Abstract

NMR and IR spectroscopy have been used to study the solvation of the dicyanamide ion in solvents with different chemical natures. The occurrence of two kinds of interaction of the N(CN)2 −ion with the solvents has been established: by means of hydrogen bonds (alcohols, chloroform) and by ion-dipole interaction (aprotic solvents).

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Authors and Affiliations

  1. Kiev University, USSR

    S. V. Garbuz, V. V. Skopenko, N. N. Gerasimchuk & A. M. Shakhvorost

Authors
  1. S. V. Garbuz
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  2. V. V. Skopenko
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  3. N. N. Gerasimchuk
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  4. A. M. Shakhvorost
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 24, No. 3, pp. 361–366, May–June, 1988.

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Garbuz, S.V., Skopenko, V.V., Gerasimchuk, N.N. et al. Solvation of tetraphenylphosphonium dicyanamide. Theor Exp Chem 24, 351–355 (1988). https://doi.org/10.1007/BF00534566

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  • DOI: https://doi.org/10.1007/BF00534566

Keywords

  • Hydrogen
  • Alcohol
  • Spectroscopy
  • Hydrogen Bond
  • Chloroform