Theoretical and Experimental Chemistry

, Volume 25, Issue 6, pp 633–637 | Cite as

Kinetics of symmetric electron exchange reaction in series of substituted nitrobenzenes: Influence of reactant structure

  • N. T. Ioffe
  • V. G. Mairanovskii


Kinetic data on symmetric electron exchange in substituted nitrobenzenes have been obtained by means of ESR. The logarithm of the electron exchange rate constant varies linearly with the square of the constant of hyperfine splitting on the nitrogen atom of the nitro group. On the basis of the results obtained, it is concluded tentatively that solvation of the nitro group plays a decisive role in the kinetics of symmetric electron exchange in this series of compounds.


Nitrogen Exchange Rate Nitrogen Atom Exchange Reaction Nitrobenzene 
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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • N. T. Ioffe
    • 1
  • V. G. Mairanovskii
    • 1
  1. 1.Scientific-Industrial Association “Vitaminy”Moscow

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