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Theoretical and Experimental Chemistry

, Volume 24, Issue 5, pp 586–590 | Cite as

Characteristics of the “strong metal-carrier interaction” using the example of influence of vanadium oxide on catalytic activity of platinum metals in CO hydrogenation

  • N. I. Il'chenko
  • Yu. I. Shmyrko
  • L. N. Raevskaya
  • G. I. Golodets
Brief Communications
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Abstract

The specific catalytic activities of metals M (M = Ru, Rh, Pd, Ir, Pt) in the hydrogenation of CO change under the influence of vanadium oxide addition. The nature of the change is determined by the ability of M to donate electrons to the oxide or to take them from the oxide. The higher the electron donor capacity the greater the degree to which the bond between CO and the M surface is weakened and the higher the catalytic activity.

Keywords

Oxide Hydrogenation Platinum Catalytic Activity Vanadium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • N. I. Il'chenko
    • 1
  • Yu. I. Shmyrko
    • 1
  • L. N. Raevskaya
    • 1
  • G. I. Golodets
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryAcademy of Sciences of the Ukrainian SSRKiev

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