Theoretica chimica acta

, Volume 28, Issue 3, pp 235–239 | Cite as

On asymptotic calculation of the exchange interaction

  • E. A. Andreev


The asymptotic calculation of the exchange interaction between two atoms with the same ionization potentials is carried out. It is established that the second term (of relative order R−1/2) of the asymptotic series becomes zero. The dependence of the atom-molecule exchange interaction on vibrational coordinates is also discussed.


Physical Chemistry Inorganic Chemistry Organic Chemistry Exchange Interaction Ionization Potential 
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Die Austauschwechselwirkung zwischen zwei Atomen mit gleichem Ionisationspotential wird asymptotisch berechnet. Es wird gezeigt, daß der zweite Term (von der relativen Ordnung R−1/2) der asymptotischen Reihe verschwindet. Die Abhängigkeit der Atom-Molekül-Austauschwechselwirkung von den Schwingungskoordinaten wird ebenfalls diskutiert.


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Copyright information

© Springer-Verlag 1973

Authors and Affiliations

  • E. A. Andreev
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of SciencesMoscow

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