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Theoretica chimica acta

, Volume 28, Issue 3, pp 235–239 | Cite as

On asymptotic calculation of the exchange interaction

  • E. A. Andreev
Commentationes

Abstract

The asymptotic calculation of the exchange interaction between two atoms with the same ionization potentials is carried out. It is established that the second term (of relative order R−1/2) of the asymptotic series becomes zero. The dependence of the atom-molecule exchange interaction on vibrational coordinates is also discussed.

Keywords

Physical Chemistry Inorganic Chemistry Organic Chemistry Exchange Interaction Ionization Potential 
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Zusammenfassung

Die Austauschwechselwirkung zwischen zwei Atomen mit gleichem Ionisationspotential wird asymptotisch berechnet. Es wird gezeigt, daß der zweite Term (von der relativen Ordnung R−1/2) der asymptotischen Reihe verschwindet. Die Abhängigkeit der Atom-Molekül-Austauschwechselwirkung von den Schwingungskoordinaten wird ebenfalls diskutiert.

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Copyright information

© Springer-Verlag 1973

Authors and Affiliations

  • E. A. Andreev
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of SciencesMoscow

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