Theoretical and Experimental Chemistry

, Volume 28, Issue 5–6, pp 312–314 | Cite as

Synergism in an organized photocatalytic system based on cadmium sulfide and titanium complexes

  • V. D. Pokhodenko
  • A. I. Kryukov
  • S. Ya. Kuchmii
  • A. V. Korzhak
  • N. F. Cuba
Article

Abstract

A nonadditive acceleration of oxidation-reduction processes has been observed in systems containing semiconductors and metal complex photocatalysts. The conditions necessary for synergism to occur have been analyzed for the example of the generation of H2 from aqueous alcoholic media with the participation of CdS and titanium(lV) complexes.

Keywords

Titanium Sulfide Cadmium Metal Complex Cadmium Sulfide 

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Literature cited

  1. 1.
    M. Grettsel (ed.), Energetic Resources of Visible Light Photochemistry and Catalysis [Russian translation], Mir, Moscow (1986).Google Scholar
  2. 2.
    A. I. Kryukov, and S. Ya. Kuchmii, Photochemistry of Transition Metal Complexes [in Russian], Nauk. Dumka, Kiev (1989).Google Scholar
  3. 3.
    V. D. Pokhodenko, A. A. Beloded, and V. G. Koshechko, Redox Reactions of Free Radicals [in Russian], Nauk. Dumka, Kiev (1977).Google Scholar
  4. 4.
    E. N. Smirnov, E. R. Savinova, and V. N. Parmon, Photocatalytic Conversion of Solar Energy [in Russian], Nauka, Novosibirsk (1985), Vol. 2, pp. 107–152.Google Scholar
  5. 5.
    A. I. Kryukov, S. Ya. Kuchmii, A. V. Korzhak, and S. V. Kulik, Teor. Eksp. Khim., 25, No. 4, 452–459 (1989).Google Scholar

Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • V. D. Pokhodenko
    • 1
  • A. I. Kryukov
    • 1
  • S. Ya. Kuchmii
    • 1
  • A. V. Korzhak
    • 1
  • N. F. Cuba
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryUkrainian Academy of SciencesKiev

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