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Kinetics of the thermal-programmed surface oxidation of vinyl chloride chemisorbed on cobalt chromite

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Abstract

A study was carried out on the kinetics of the temperature-programmed surface oxidation of vinyl chloride chemisorbed on cobalt chromite. The existence of two key intermediate surface compounds resulting from decomposition of the chlorohydrocarbon at the double bond was established. A kinetic model was obtained for the step involving the regeneration of the catalyst.

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References

  1. V. M. Vlasenko, O. G. Chernitskii, O. V. Konopatskii, and V. L. Chernobrivets, Ukr. Khim. Zh., 59, No. 6, 584–588 (1993).

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  3. V. I. Yakerson and V. V. Rozanov, Investigation of Catalytic Systems by Thermal Desorption and Thermal Chromatography [in Russian], VINITI, Moscow (1974).

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  4. O. V. Konopatskii, O. G. Chernitskii, and A. I. Tripol'skii, Teor. Éksp. Khim., 449–455 (1993).

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of Ukraine, Kiev

    O. V. Konopatskii, O. G. Chernitskii & V. M. Vlasenko

Authors
  1. O. V. Konopatskii
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  2. O. G. Chernitskii
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  3. V. M. Vlasenko
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Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 29, No. 5, pp. 462–467, September–October, 1993.

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Konopatskii, O.V., Chernitskii, O.G. & Vlasenko, V.M. Kinetics of the thermal-programmed surface oxidation of vinyl chloride chemisorbed on cobalt chromite. Theor Exp Chem 29, 309–312 (1994). https://doi.org/10.1007/BF00531469

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  • DOI: https://doi.org/10.1007/BF00531469

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