Abstract
The authors survey their research on the reactions of monophenylacetylenes and diphenylacetylenes coordinated to several metallic centers. The ligand structure and the coordination principle determine whether the C≡C bond order is reduced almost to first order or there is polar breakage of that bond, which is also affected by the nature of the metal, the number of nuclei, and the metal core structure and geometry.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
R. Tsumura and N. Hagihara, Bull. Chem. Soc. Jpn., 38, No. 3, 1901–1903 (1965).
O. S. Mills and B. W. Shaw, J. Organomet. Chem., 11, No. 1, 595 (1969).
M. J. Bruse, Chem. Rev., 91, No. 2, 197–257 (1991).
R. D. Adams, Z. Li, P. Swepston, et al., J. Amer. Chem. Soc., 114, No. 26, 10657 (1992).
S. Otsuka and A. Nakamura, Adv. Organomet. Chem., 14, 245–283 (1976).
T. J. Henly, Coord. Chem. Rev., 93, 269–295 (1989).
A. D. Shaposhnikova, R. A. Stadnichenko, A. A. Pasynskii, et al., Zh. Neorg. Khim. 38, No. 3, 455–465 (1993).
P. O. Nubel and T. L. Brown, Organometallics, 3, 29 (1984).
A. D. Shaposhnikova, R. A. Stadnichenko, V. K. Bel'skii, et al., Metalloor. Khim. 1, No. 4, 945–951 (1988).
I. L. Eremenko, A. D. Shaposhnikova, R. A. Stadnichenko, et al., Zh. Neor. Khim., 37, No. 3, 574–582 (1992).
W. Hubel and E. H. Braye, J. Inorg. Chem., 10, 250–268 (1959).
A. B. Antonova and A. A. Ioganson, Usp. Khim., 58, No. 7, 1197–1229 (1989).
A. D. Shaposhnikova, R. A. Stadnichenko, A. A. Pasynskii, et al., Metalloorg. Khim., 2, No. 4, 932–933 (1989).
E. Sappa, A. Tiripicchio, P. Braunstein, et al., Chem. Rev., 83, 203–215 (1983).
A. D. Shaposhnikova, G. L. Kamalov, R. A. Stadnichenko, et al., J. Organomet. Chem., 405, 111–120 (1991).
C. Barner-Thorsen, E. Rosenberg, A. M. M. Landfredi, et al., Inorg. Chem., 20, No. 11, 4306–4311 (1981).
E. Sappa, A. Tiripicchio, and C. M. Tiripicchio, Inorg. Chim. Acta, 42, No. 2, 183–190 (1980).
O. A. Kizas, Intramolecular Rearrangement and Activation for Carbonyl and Carbon Ligands in Triosmium Clusters: Ph. D. Thesis [in Russian], Moscow (1989).
A. D. Shaposhnikova, R. A. Stadnichenko, G. L. Kamalov, et al., J. Organomet. Chem., 453, 279–281 (1993).
W. Bernhardt, C. Schnering, and H. Vahrenkamp, Angew. Chem., 98, No. 3, 285–286 (1986).
R. B. King, Ann. N. Y. Acad. Sci., 295, 135 (1977).
J. T. Park, J. R. Shapley, M. R. Churchill, et al., J. Amer. Chem. Soc., 105, 6182.
M. H. Chisholm, Polyhedron, 2, 716 (1993).
A. D. Shaposhnikova, M. V. Drab, I. L. Eremenko, et al., Metalloorg. Khim. 3, No. 3, 699–700 (1990).
A. D. Shaposhnikova, M. V. Drab, G. L. Kamalov, et al., J. Organomet. Chem., 429, 109–118 (1992).
S. E. Nefedov, A. A. Pasynskii, I. L. Eremenko, et al., J. Organomet. Chem., 384, 279–281 (1990).
Author information
Authors and Affiliations
Additional information
Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 29, No. 5, pp. 378–394, September–October, 1993
We are indebted to Academician V. D. Pokhodenko, Ukrainian Academy of Sciences, for the attention he has given to this research.
Rights and permissions
About this article
Cite this article
Shaposhnikova, A.D., Stadnichenko, R.A., Teplova, M.V. et al. Phenylacetylene coordination in heterometallic clusters: multiple-bond activation models. Theor Exp Chem 29, 247–259 (1994). https://doi.org/10.1007/BF00531459
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00531459