Abstract
Simple analytic expressions have been obtained for the more common types of selective oxidation mechanisms provided by oxide catalysts, which relate the product yield to the extent of reaction in a flow or gradient-free reactor. It is shown to be possible to increase the yield by the use of combined catalyst layers.
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M. I. Temkin and N. V. Kul'kova, “A laboratory ideal-displacement reactor,” Kinet. Katal. 10, No. 2, 461–463 (1969).
N. V. Kul'kova, L. P. Levchenko, I. M. Arkhipov, et al, “A single-row ideal-displacement reactor,” Khim. Promst., No. 9, 16–20 (1968).
G. P. Korneichuk, V. P. Stasevich, and G. G. Girushtin, “A block multichannel ideal-displacement reactor,” Kinet. Katal., 18, No. 1, 244–247 (1977).
S. L. Kiperman, “Kinetic aspects of selectivity,” Kinet Katal., 22, No. 1, 30–44 (1981).
O. M. Il'inich and A. A. Ivanov, “A kinetic analysis of the effects of promoters on the properties of vanadium-titanium catalysts for oxidizing o-xylent,” Kinet. Katal., 24, No. 3, 613–617 (1983).
Yu. I. Pyatnitskii, “Gas-phase partial oxidation of aromatic hydrocarbons on heterogeneous catalysts,” Probl. Kinet. Katal., 19, 132–146 (1985).
G. I. Golodets, Heterogeneously Catalyzed Oxidation of Organic Compounds [in Russian], Naukova Dumka, Kiev (1978).
M. I. Temkin and N. V. Kul'kova, “The oxidation of ethylene to ethylene oxide on silver,” Probl. Kinet. Katal., 19, 73–85 (1985).
T. G. Vazhnova, V. N. Korchak, V. I. Timoshenko, et al., “Kinetic laws in the oxidation of isobutylene to methacrolein on a bismuth-cobalt-iron-molybdenum catalyst,” Kinet. Katal. 26, No. 6, 1378–1386 (1985).
V. A. Roiter, G. P. Korneichuk, V. P. Ushakova, and N. A. Stukanovskaya, The Catalytic Oxidation of Naphthalene [in Russian], Izd. Akad. Nauk Ukr. SSR, Kiev (1963).
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 3, pp. 345–349, May–June, 1987.
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Pyatnitskii, Y.I., Borovik, V.V. Calculating product yields in selective catalytic oxidation in flow and gradient-free reactors. Theor Exp Chem 23, 318–322 (1987). https://doi.org/10.1007/BF00531386
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DOI: https://doi.org/10.1007/BF00531386