Abstract
Data are given on the catalytic activity of a series of cobalt coordination compounds with macrocyclic and acyclic Ligands of different structures in radical polymerization reactions of methacrylic monomers. The influence of various factors (especially the structure of the ligand) on the manifestation of catalytic properties of the compounds studied is discussed.
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 3, pp. 317–322, May–June, 1987.
The authors wish to express their gratitude to E.-G. Eger for kindly providing samples of compound VI, VII, and IX and also to I. P. Rudakova, for the sample of compound X.
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Gridnev, A.A., Lampeka, Y.D., Smirnov, B.R. et al. Structural features of macrocyclic cobalt complexes —catalysts of chain transfer to a monomer in radical polymerization. Theor Exp Chem 23, 293–297 (1987). https://doi.org/10.1007/BF00531382
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DOI: https://doi.org/10.1007/BF00531382