Abstract
Thermal deoxygenation under vacuum has been examined for free oxygenated cobalt complexes formed with phenanthroline, histidine, and histamine and also for those attached to aerosil; mass spectrometry has been applied to the products. The free compounds are deoxygenated in accordance with the Roginskii equation f(α) = (1−α)2/3 in a certain range. Deoxygenation for the grafted complexes is described by an equation for nucleation and one-dimensional growth f(α) = 1−α. The kinetic parameters have been determined.
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 23, No. 3, pp. 311–317, May–June, 1987.
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Pokrovskii, V.A., Bratushko, Y.I., Yakubovich, T.N. et al. Nonisothermal deoxygenation of cobalt complexes in free form and attached to aerosil. Theor Exp Chem 23, 289–293 (1987). https://doi.org/10.1007/BF00531381
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DOI: https://doi.org/10.1007/BF00531381