Skip to main content
Log in

Asymmetric polymethine dyes based on thiazolo[3,2-a]quinoxalinium salts

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Asymmetric carbocyanine dyes, the solutions of which are characterized by the presence of several absorption bands in the visible and near-IR regions, were synthesized from 4,5-dimethyl-1-oxo-2-phenyl-1,5-dihydrothiazolo[3,2-a]quinoxalin-3-ium perchlorate. Their deep color is due both to a more effective length of the condensed heterocyclic system and to the strong interaction of the electronic transitions, localized on the polymethine chain and on the heterocyclic ring.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. B. Fedotov and N. N. Romanov, Khim. Geterotsikl. Soedin., No. 6, 842 (1990).

    Google Scholar 

  2. S. F. Mason, “Color and electronic state of organic molecules,” in: Chemistry of Synthetic Dyes, Vol. 3, K. Venkataroman (ed.) [Russian translation], Khimiya, Leningrad (1975), p. 1817.

    Google Scholar 

  3. G. G. Dyadyusha and A. D. Kachkovskii, Ukr. Khim. Th., 44, No. 9, 948 (1978).

    Google Scholar 

  4. L. G. S. Brooker, R. H. Sprague, and H. W. J. Cressman, J. Am. Chem. Soc., 67, No. 11, 1889 (1945).

    Google Scholar 

  5. Ya. B. Shteinberg, Khim. Geterotsikl. Soedin., No. 3, 340 (1973).

    Google Scholar 

  6. L. G. S. Brooker, A. L. Sklar, H. W. J. Cressman, G. H. Keyes, L. A. Smith, R. H. Spraque, E. Van Lare, G. Van Zandt, F. L. White, and W. W. Williams, J. Am. Chem. Soc., 67, No. 11, 1875 (1945).

    Google Scholar 

  7. A. I. Kipryanov, Color and Structure of Cyanine Dyes [in Russian], Naukova Dumka, Kiev (1979).

    Google Scholar 

  8. A. I. Kipryanov, Usp. Khim., No. 7, 1283 (1971).

    Google Scholar 

  9. S. G. Fridman and A.I. Kipryanov, Zh. Org. Khim., 4, No. 4, 696 (1968).

    Google Scholar 

  10. I. L. Mushkalo and L. S. Turova, Ukr. Khim. Th., 43, No. 7, 742 (1977).

    Google Scholar 

  11. K. B. Fedotov and N. N. Romanov, Khim. Geterotsikl. Soedin., No. 12, 1680 (1989).

    Google Scholar 

  12. F. M. Hamer, The Cyanine Dyes and Related Compounds, Interscience, New York (1964), p. 132.

    Google Scholar 

  13. Yu. L. Briks, N. N. Romanov, and A. V. Turov, Zh. Org. Khim., 26, No. 12, 2591 (1990).

    Google Scholar 

  14. G. A. Reynolds and J. A. Van Allan, J. Org. Chem., 34, No. 9, 2736 (1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1113–1116, August, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fedotov, K.V. Asymmetric polymethine dyes based on thiazolo[3,2-a]quinoxalinium salts. Chem Heterocycl Compd 28, 937–940 (1992). https://doi.org/10.1007/BF00531331

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00531331

Keywords

Navigation