Abstract
On the basis of a three-step mechanism of ethylene homopolymerization, the processes of activation of the catalyst particles and filling of their pores by the polymer were studied by means of mathematical simulation and a computational experiment. The indices of the polymerization process were determined as a function of the change in its main controlled variables.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. K. Godunov and V. S. Ryaben'kii, Introduction to the Theory of Difference Schemes [in Russian], Fizmatgiz, Moscow (1967).
E. Oran and J. Boris, Numerical Modeling of Reacting Flows [Russian translation], Mir, Moscow (1990)
N. N. Yanenko, N. T. Danaev, and V. D. Liseikin, Chisl. Metody. Mekh. Splosh. Sredy, 8, No. 4, 157–163 (1977).
V. D. Liseikin and N. N. Yanenko, Chisl. Metody. Mekh. Splosh. Sredy, 8, No. 7, 100–104 (1977).
V. D. Liseikin and N. N. Yanenko, Chisl. Metody. Mekh. Splosh. Sredy, 7, No. 2, 75–82 (1976).
Author information
Authors and Affiliations
Additional information
Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 29. No. 3, pp. 280–285, May–June, 1993.
Rights and permissions
About this article
Cite this article
Orlik, V.N., Kolesnik, Y.V. Mechanism of gaseous polymerization of ethylene on a single grain of catalyst. Theor Exp Chem 29, 188–191 (1994). https://doi.org/10.1007/BF00531182
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00531182