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Selective determination of 2,3,7,8-tetrachlorodibenzo-p-dioxin in the presence of a large excess of other polychlorinated dibenzodioxins and polychlorinated dibenzofurans

Selektive Bestimmung von 2,3,7,8-Tetrachlordibenzo-p-dioxin in Gegenwart eines großen Überschusses anderer polychlorierter Dibenzodioxine und polychlorierter Dibenzofurane

  • Original Papers
  • Dioxins and Dibenzofurans
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Zusammenfassung

Ein Verfahren wird beschrieben, das die selektive Abtrennung von 2,3,7,8-TCDD aus einer Mischung von allen PCDDs und PCDFs erlaubt. Dies geschieht durch Fraktionierung an Alumina Woelm B Super I, wodurch eine getrennte Elution aller PCDDs und PCDFs von 2,3,7,8-TCDD erreicht werden kann. Dieses Verfahren erlaubt die quantitative Bestimmung von 2,3,7,8-TCDD mit höherer Nachweisempfindlichkeit in Proben, die andere TCDDs bzw. PCDDs und PCDFs in extremen Überschüssen im Vergleich zu 2,3,7,8-TCDD enthalten. Am Beispiel der Bestimmung von 2,3,7,8-TCDD in Pentachlorphenol und in einem Produktionsrückstand von 2,4-Dichlorphenol wird die praktische Anwendbarkeit nachgewiesen.

Summary

A procedure is described for the selective separation of 2,3,7,8-TCDD from all other PCDDs and PCDFs. For this purpose the mixture of PCDDs and PCDFs is fractionated on Alumina Woelm B Super I in such a manner that all PCDDs and PCDFs are eluted prior to 2,3,7,8-TCDD. This procedure allows a more sensitive quantitative determination of 2,3,7,8-TCDD in samples which contain 2,3,7,8-TCDD only as a very minor fraction of the other TCDDs or PCDDs and PCDFs. Determination of 2,3,7,8-TCDD in pentachlorophenol and in a waste sample from 2,4-dichlorophenol production by this procedure is described.

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References

  1. Oehme M, Kirschmer P (1984) Anal Chem 56:2754–2759

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  2. Hagenmaier H, Berchtold A, Proceedings of the 5th Symposium on Chlorinated Dioxins and Related Compounds, Bayreuth 1985, submitted to Chemosphere

  3. Buser HR, Rappe C (1984) Anal Chem 56:442–448

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  4. Lamparski LL, Nestrick TJ (1980) Anal Chem 52:2045–2054

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Authors and Affiliations

  1. Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-7400, Tübingen, Federal Republic of Germany

    Hanspaul Hagenmaier, Hermann Brunner, Roland Haag & Michael Kraft

Authors
  1. Hanspaul Hagenmaier
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  2. Hermann Brunner
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  3. Roland Haag
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  4. Michael Kraft
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Additional information

This work was supported by the Ministerium für Ernährung, Landwirtschaft, Umwelt und Forsten, Baden-Württemberg.

The skilfull technical assistance of Roland Kerzenmacher is acknowledged.

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Hagenmaier, H., Brunner, H., Haag, R. et al. Selective determination of 2,3,7,8-tetrachlorodibenzo-p-dioxin in the presence of a large excess of other polychlorinated dibenzodioxins and polychlorinated dibenzofurans. Z. Anal. Chem. 323, 24–28 (1986). https://doi.org/10.1007/BF00531125

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  • DOI: https://doi.org/10.1007/BF00531125

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