Abstract
The promotion of hydrogenation of CO to methanol and dimethyl ether by oxygen over supported palladium catalysts increases with increasing oxygen content in the reaction mixture, but the system, becomes less stable with time. A high level of selectivity with respect to oxygen-containing compounds may be achieved by periodic introduction of oxygen into the synthesis gas.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
Yu. I. Pyatnitskii, G. V. Filonenko, T. M. Shaprinskaya, et al., All-Union Conf. Chemical Syntheses Based on One-Carbon Molecules, Moscow, November 30-December 3, 1987. Abstr. Nauka, Moscow (1987), p. 21.
Yu. I. Pyatnitskii, G. V. Filonenko, T. M. Shaprinskaya, et al., Neftekhimiya, 29, No. 3, 374–383 (1989).
Yu. I. Pyatnitskii, G. V. Filonenko, V. P. Stasevich, et al., Teor. Éksp. Khim., 25, No. 5, 557–563 (1989).
G. V. Filonenko, T. M. Shaprinskaya, Yu. I. Pyatnitskii, et al., Teor. Éksp. Khim., 28, No. 4, 354–358 (1992).
P. I. Berlowitz and D. V. Goodman. J. Catal., 108, No. 2, 364–368 (1987).
T. Engell and G. Ertl, Chem. Phys. Lett., 54, No. 1, 95–98 (1978).
Author information
Authors and Affiliations
Additional information
Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 28, No. 4, pp. 364–367, July–August, 1992.
Rights and permissions
About this article
Cite this article
Filonenko, G.V., Shaprinskaya, T.M., Pyatnitskii, Y.I. et al. Non-stationary effects during conversion of synthesis gas containing added oxygen over supported palladium catalysts. Theor Exp Chem 28, 283–285 (1993). https://doi.org/10.1007/BF00530291
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00530291