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Associative model of activation of diacyl peroxides by chloride salts of amines

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Abstract

Intermolecular and ion-molecule interactions of benzoyl peroxide with tetraethylammonium chloride in an acetonitrile medium have been investigated by means of NMR. The types of association of the diacyl peroxide with ammonium chloride have been modeled by means of the MNDO method. The state of the peroxide molecule in the associate has been analyzed.

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Literature cited

  1. M. A. Turovskii, S. Yu. Tselinskii, I. O. Opeida, and R. V. Kucher, Dopov. Akad. Nauk Ukr. RSR, Ser. B, No. 3, pp. 131–134 (1991).

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  2. E. M. Gavryliv, N. A. Turovskii, R. V. Kucher, et al., Dokl. Akad. Nauk Ukr. SSR, Ser. B, No. 11, 32–34 (1990).

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Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic Chemistry and Coal-Tar Chemistry, Ukrainian Academy of Sciences, Donetsk

    N. A. Turovskii, S. Yu. Tselinskii, Yu. E. Shapiro & A. R. Kalyuskii

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  1. N. A. Turovskii
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  2. S. Yu. Tselinskii
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  3. Yu. E. Shapiro
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  4. A. R. Kalyuskii
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 28, No. 4, pp. 320–323, July–August, 1992.

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Turovskii, N.A., Tselinskii, S.Y., Shapiro, Y.E. et al. Associative model of activation of diacyl peroxides by chloride salts of amines. Theor Exp Chem 28, 251–253 (1993). https://doi.org/10.1007/BF00530282

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  • DOI: https://doi.org/10.1007/BF00530282

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