Theoretica chimica acta

, Volume 23, Issue 1, pp 39–51 | Cite as

Perturbation treatment of Hartree-Fock equations for resonance states of three electron atoms and ions

  • I. Eliezer
  • A. Moualem
Commentationes

Abstract

A perturbation treatment of the Hartree-Fock equations using the inverse nuclear charge as perturbation parameter has been applied to several quasibound and metastable states of three-electron atoms and ions. The deviations of the results from the experimental values are discussed. The method should be particularly useful for heavier atoms and ions.

Keywords

Physical Chemistry Inorganic Chemistry Organic Chemistry Metastable State Resonance State 

Zusammenfassung

Eine störungstheoretische Behandlung der Hartree-Fock-Gleichungen, bei der die inverse Kernladung als Störungsparameter benutzt wird, wird für verschiedene quasibindende und metastabile Zustände von Atomen und Ionen mit drei Elektronen durchgeführt. Die Abweichung von den experimentellen Werten wird diskutiert. Die Methode sollte besonders für schwerere Atome und Ionen nützlich sein.

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Copyright information

© Springer-Verlag 1971

Authors and Affiliations

  • I. Eliezer
    • 1
  • A. Moualem
    • 1
  1. 1.Department of ChemistryTel-Aviv UniversityTel-AvivIsrael

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