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Chemistry of Heterocyclic Compounds

, Volume 28, Issue 10, pp 1198–1202 | Cite as

Polarographic investigation of the mobility of halogen atoms in halogen-substituted components of nucleic acids

  • V. P. Kadysh
  • Yu. L. Kaminskii
  • L. N. Rumyantseva
  • V. L. Efimova
  • Ya. P. Stradyn'
Article
  • 32 Downloads

Abstract

In order to establish quantitatively the reducibility of halogen-substituted components of nucleic acids, the half-wave potentials (E1/2) of their electrochemical reduction have been determined. The electrochemical reduction of all compounds takes place in the interval from −0.5 to −1.8 V and consists in the splitting off of the halogen atom (iodine, bromine) from the given molecule. The iodine derivatives are reduced much more readily (500–800 mV) than the bromine derivatives.

Keywords

Organic Chemistry Iodine Nucleic Acid Bromine Halogen 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • V. P. Kadysh
    • 1
    • 2
  • Yu. L. Kaminskii
    • 1
    • 2
  • L. N. Rumyantseva
    • 1
    • 2
  • V. L. Efimova
    • 1
    • 2
  • Ya. P. Stradyn'
    • 1
    • 2
  1. 1.Latvian Institute of Organic SynthesisRiga
  2. 2.V. G. Khlopin Radium InstituteSt. Petersburg

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