Advertisement

Chemistry of Heterocyclic Compounds

, Volume 28, Issue 3, pp 279–282 | Cite as

Reaction of 5,5-dimethyl-4-cyanomethylene-1,3-oxathiolan-2-one with amines and ammonia

  • A. G. Mal'kina
  • Yu. M. Skvortsov
  • E. I. Moshchevitina
  • V. K. Bel'skii
  • B. A. Trofimov
Article
  • 29 Downloads

Abstract

A simple method for the synthesis of 5,5-dimethyl-4-cyanomethylene-2-cyanomethyl-2-[1-methyl-1-(carbamoyloxy)ethyl]-1,3-dithiolanes was developed on the basis of the reaction of 5,5-dimethyl-4-cyanomethylene-1,3-oxathiolan-2-one with amines (primary and secondary) and ammonia.

Keywords

Ammonia Ethyl Organic Chemistry Dithiolanes Carbamoyloxy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    D. D. Reynolds, M. K. Massad, D. I. Fields, and D. L. Johnson, J. Org. Chem., 26, 5109 (1961).Google Scholar
  2. 2.
    D. D. Reynolds, D. L. Fields, and D. L. Johnson, J. Org. Chem., 26, 5111 (1961).Google Scholar
  3. 3.
    D. D. Reynolds, D. L. Fields, and D. L. Johnson, J. Org. Chem., 26, 5116 (1961).Google Scholar
  4. 4.
    A. G. Mal'kina, Yu. M. Skvortsov, E. I. Moshchevitina, V. K. Bel'skii, and B. A. Trofimov, Khim. Geterotsikl. Soedin., No. 6, 855 (1989).Google Scholar
  5. 5.
    A. S. Nakhmanovich and V. N. Elokhina, Khim. Geterotsikl. Soedin., No. 3, 291 (1987).Google Scholar
  6. 6.
    V. N. Drozd, A. S. Vyazgin, and E. N. Komarova, Zh. Org. Khim., 22, No. 11, 2443 (1986).Google Scholar
  7. 7.
    S. T. Gough, German offen. No. 2,028,597; Chem. Abstr., 74, 76,429 (1971).Google Scholar
  8. 8.
    E. G. Teach, US Patent No. 3,759,952; Chem. Abstr., 79, 146,529 (1973).Google Scholar
  9. 9.
    A. G. Mal'kina, Yu. M. Skvortsov, E. I. Moshchevitina, and V. A. Trofimov, Zh. Org. Khim., 24, No. 11, 2452 (1988).Google Scholar
  10. 10.
    A. Gordon and R. Ford, The Chemist's Guide [Russian translation], Mir, Moscow (1976), p. 129.Google Scholar

Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • A. G. Mal'kina
    • 1
  • Yu. M. Skvortsov
    • 1
  • E. I. Moshchevitina
    • 1
  • V. K. Bel'skii
    • 1
  • B. A. Trofimov
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchRussian Academy of SciencesIrkutsk

Personalised recommendations