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Bindungsverhältnisse und Elektronenverteilung im Br 2−4 -Ion

Electronic structure, binding energy and charge distribution of Br 2−4

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Abstract

The linear ions Br 2−4 which has been discovered for the first time by Siepmann and Schnering [13] in W6Br16 have been studied theoretically using the free electron model for the valence electrons. Electronic structure, binding energy and charge distribution show that Br 2−4 is a typical electron deficient compound stabilized by a 4c-6e bond.

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Authors and Affiliations

  1. Sektion Chemie der Friedrich-Schiller-Universität Jena, DDR

    H. Müller

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  1. H. Müller
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Herrn Prof. Dr. H. Dunken bin ich für sein stetes Interesse und die rege Anteilnahme an diesen Modellrechnungen zu großem Dank verpflichtet.

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Müller, H. Bindungsverhältnisse und Elektronenverteilung im Br 2−4 -Ion. Theoret. Chim. Acta 21, 110–114 (1971). https://doi.org/10.1007/BF00529095

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  • DOI: https://doi.org/10.1007/BF00529095

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