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Chemistry of Heterocyclic Compounds

, Volume 29, Issue 7, pp 735–743 | Cite as

Nucleophilic reactions of heterylsilanes and heterylgermanes (review)

  • E. Lukevits
  • L. Borisova
  • V. Gevorgyan
Article

Abstract

We generalize data on the reactivity of furyl-, dihydrofuryl-, tetrahydrofuryl-, dihydropyranyl-, and tetrahydropyranylsilanes and -germanes in reactions with nucleophilic reagents. We show that upon reaction of heterosilanes and heterogermanes with O-, N-, C-, and H-nucleophiles, sequential substitution of the heterocycles occurs at the nucleophilic group. We consider the rearrangement of (2-tetrahydrofuryl)- and (2-tetrahydropyranyl) hydrosilanes with ring expansion, and also rearrangement of linear acyloxymethyl- and halomethylhydrosilanes to the corresponding acyloxy- and halosilanes.

Keywords

Organic Chemistry Furyl Nucleophilic Reagent Nucleophilic Reaction Ring Expansion 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1994

Authors and Affiliations

  • E. Lukevits
    • 1
  • L. Borisova
    • 1
  • V. Gevorgyan
    • 1
  1. 1.Latvian Institute of Organic SynthesisRiga

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