Chemistry of Heterocyclic Compounds

, Volume 29, Issue 1, pp 33–39 | Cite as

Sulfur-containing derivatives of thiolan-1,1-dioxide 3. Reactions of salts of 2-(n,n-dialkyl)iminio-5,5-dioxoperhydrothieno[3,4-d]-1,3-dithiolans with bases

  • V. I. Slutskii
  • Yu. B. Bezuglyi


Salts of condensed 2-(N,N-dialkyl)iminio-1,3-dithiolan and 1,1-dioxothiolan rings are converted in alkaline media to 1,1-dioxothiolen esters of N,N-dialkyldithiocarbamic acids and into unsaturated bicyclic compounds. The latter are formed when the initial salts contain a bromine atom β to the sulfonyl group.


Ester Dioxide Organic Chemistry Bromine Alkaline Medium 
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Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • V. I. Slutskii
    • 1
  • Yu. B. Bezuglyi
    • 1
  1. 1.Institute of Bioorganic Chemistry and PetrochemistryKiev

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