Abstract
General expressions are derived for the complex scattering phases, with allowance for change in the relative velocity of the partners within the Franck-Condon region. A value is deduced for the cross section for elastic scattering with dissociative charge transfer. The scattering of K atoms by Br2 molecules is considered as an example.
Similar content being viewed by others
References
E. E. Nikitin, TEKh [Theoretical and Experimental Chemistry], 4, 593, 1968.
D. R. Herschbach, in: Molecular Beams, ed. J. Ross., Intersci. Publ., p. 319, 1966.
L. D. Landau and E. M. Lifshits, Quantum Mechanics [in Russian], Moscow, Fizmatgiz, 1963.
Yu. N. Demkov, DAN SSSR, 116, 1076, 1966.
V. I. Osherov, DAN SSSR, 168, 1291, 1966.
E. Jahnke and F. Emde, Tables of Functions [Russian translation], Gostekhizdat, 1948.
J. G. Winans and E. C. G. Stueckelberg, Proc. Nat. Acad. Sci. Amer., 14, 867, 1928.
Author information
Authors and Affiliations
Additional information
I am indebted to M. Ya. Ovchinnikov for numerous discussions.
Rights and permissions
About this article
Cite this article
Nikitin, E.E. Quantum effects in electron harpooning. Theor Exp Chem 4, 482–485 (1971). https://doi.org/10.1007/BF00527024
Issue Date:
DOI: https://doi.org/10.1007/BF00527024