Theoretical and Experimental Chemistry

, Volume 16, Issue 6, pp 549–553 | Cite as

Mechanism of vibrational relaxation of CH3F with high concentrations of excited molecules

  • E. N. Chesnokov
  • V. N. Panfilov
Article
  • 14 Downloads

Keywords

Excited Molecule Vibrational Relaxation 

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Literature cited

  1. 1.
    L. N. Krasnoperov, E. N. Chesnokov, and V. N. Panfilov, “The vibrational activation energy of the reaction of Br(2P3/2) with CH3F,” Chem. Phys., 42, No. 3, 345–353 (1979).Google Scholar
  2. 2.
    L. N. Krasnoperov and V. N. Panfilov, “The role of electronic and vibrational energy in the reaction Cl(2P3/2,1/2) + CH3F,” Teor. Eksp. Khim., 15, No. 4, 348–358 (1979).Google Scholar
  3. 3.
    E. N. Chesnokov, V. N. Shcherbinina, and V. N. Panfilov, “Dependence of rate of vibrational relaxation of CH3F on equilibrium and vibrational temperatures,” Zh. Eksp. Teor. Fiz., 75, No. 12, 2066–2074 (1978).Google Scholar
  4. 4.
    B. F. Gordiets, Sh. S. O. Mamedov, A. I. Osipov, and L. A. Shelepin, “Distribution of vibrational energy in gas mixtures,” Teor. Eksp. Khim., 9, No. 4, 460–470 (1973).Google Scholar
  5. 5.
    I. Shamah and G. W. Flynn, “Translational and vibrational energy distributions in metastable laser pumped polyatomic molecules,” J. Chem. Phys., 69, No. 6, 2474–2491 (1978).Google Scholar
  6. 6.
    A. S. Biryukov and B. F. Gordiets, “Kinetic equations of relaxation of vibrational energy in a mixture of polyatomic gases,” Zh. Prikl. Mekh. Tekh. Fiz., No. 6, 29–37 (1972).Google Scholar
  7. 7.
    A. I. Osipov, “Relaxation of vibrational energy in binary mixture of diatomic gases,” Zh. Prikl. Mekh. Tekh. Fiz., No. 1, 41–46 (1964).Google Scholar
  8. 8.
    C. E. Treanor, J. W. Rich, and R. G. Rehm, “Vibrational relaxation of anharmonic oscillators with exchange-dominated collisions,” J. Chem. Phys., 48, No. 4, 1798–1807 (1968).Google Scholar
  9. 9.
    E. E. Nikitin and A. I. Osipov, “Vibrational relaxation in gases,” Itogi Nauki Tekh., Kinet. Katal. (Nauka, Moscow), Vol. 4 (1977).Google Scholar
  10. 10.
    E. Weitz and G. W. Flynn, “Partial vibration energy transfer map for methyl fluoride: a laser fluorescence study,” J. Chem. Phys., 58, No. 7, 2781–2793 (1973).Google Scholar
  11. 11.
    R. E. McNair, S. F. Fulghum, G. W. Flynn, and M. S. Feld, “Energy storage and vibrational heating in CH3F following intense excitation,” Chem. Phys. Lett., 48, No. 2, 241–244 (1977).Google Scholar
  12. 12.
    E. Weitz and G. W. Flynn, “Deactivation of laser excited CH3F in CH3F-X mixtures,” J. Chem. Phys., 58, No. 7, 2679–2683 (1973).Google Scholar
  13. 13.
    M. Kneba and J. Wolfrum, “Reactions of molecules in certain vibrational states. V. Vibrational motion of polyatomic molecules in electronic ground state,” Ber. Bunsenges. Phys. Chem., 81, No. 12, 1275–1283 (1977).Google Scholar

Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • E. N. Chesnokov
    • 1
  • V. N. Panfilov
    • 1
  1. 1.Institute of Chemical Kinetics and CombustionSiberian Branch of the Academy of Sciences of the USSRNovosibirsk

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