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Theoretica chimica acta

, Volume 3, Issue 1, pp 69–96 | Cite as

Atomic wave functions for the configurations snpm studied by the projection operator technique

  • Jean -Louis Calais
  • Jan Linderberg
Article

Abstract

Tables of angular momentum wave functions and energy matrices for the atomic configurations sn pm are given in the cases of strong, weak and intermediate coupling. Also the transformation matrices between LS- and jj-coupling are calculated.

All these calculations are carried out as an application of the projection operator method for angular momenta, introduced by Löwdin.

Keywords

Organic Chemistry Wave Function Angular Momentum Operator Technique Projection Operator 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Résumé

On a calculé des fonctions propres du moment cinétique ainsi que les matrices correspondantes de l'énergie, pour les configurations atomiques sn pm. Les trois types de couplage, LS, jj et intermédiaire ont été étudiés, ainsi que les matrices de transformation entre ces couplages. Pour tous ces calculs on a utilisé la méthode des projecteurs pour le moment cinétique, introduite par Löwdin.

Zusammenfassung

Eigenfunktionen des Drehimpulses und entsprechende Energiematrizen für die Atomkonfigurationen sn pm sind für die drei Kopplungsfälle, LS, jj und intermediär tabelliert. Matrizen für Transformationen zwischen LS- und jj-Kopplung werden angegeben. Alle diese Rechnungen sind auf die von Löwdin eingeführte Projektionsoperatormethode gegründet.

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References

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Copyright information

© Springer-Verlag 1965

Authors and Affiliations

  • Jean -Louis Calais
    • 1
  • Jan Linderberg
    • 1
  1. 1.Quantum Chemistry GroupUppsala UniversityUppsalaSweden

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