Abstract
The electronic spectrum of a solution of the copper complex of acetylacetone as well as the spectra observed with polarized light of single crystals of the complex are reinvestigated. The observed bands are interpreted by the crystal-field theory.
Zusammenfassung
Das Elektronenspektrum einer Lösung des Kupferkomplexes von Acetylaceton sowie die mit polarisiertem Licht beobachteten Spektren von Einkristallen des Komplexes werden einer erneuten Untersuchung unterzogen. Die beobachteten Banden werden an Hand der Kristallfeld-Theorie gedeutet.
Résumé
Le spectre électronique du complexe de cuivre d'acétylacétone ainsi que les spectres — observés à l'aide de lumière polarisée — des cristaux uniques du complexe sont soumis à une nouvelle investigation. Les bandes trouvées sont interprétées suivant la théorie du champ cristallin.
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Literature
Davydov, A. S.: Theory of molecular excitons, McGraw-Hill Book Cy. Inc. 1962.
Ferguson, J.: J. chem. Physics 34, 1609 (1961).
Gray, H. B., and C. J. Ballhausen: J. Am. chem. Soc. 85, 260 (1963).
Piper, T. S., and R. L. Belford: Mol. Physics 5, 169 (1962).
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Dijkgraaf, C. Interpretation of the polarized absorption spectra of single crystals of copper acetylacetonate. Theoret. Chim. Acta 3, 38–44 (1965). https://doi.org/10.1007/BF00526531
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DOI: https://doi.org/10.1007/BF00526531