Skip to main content
SpringerLink
Log in

Structure of 6-β-[(hexahydro-1H-azepin-1-yl)methyleneamino]penicillanic acid sulfoxide

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The oxidation of 6-β-[(hexahydro-1H-azepin-1-yl)methyleneamino]penicillanic acid with potassium periodate or m-chloroperbenzoic acid leads to the corresponding sulfoxide. Its structure was proved by alternative synthesis by splitting out the N-phenylacetyl group from the benzylpenicillin sulfoxide and condensation of the 6-aminopenicillanic acid sulfoxide with N-formylhexamethyleneimine dibutylacetal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. R. D. G. Cooper, P. V. De Marco, J. C. Cheng, and N. D. Jones, J. Am. Chem. Soc., 91, 1408 (1969).

    Google Scholar 

  2. R. D. G. Cooper, P. V. De Marco, and D. O. Spry, J. Am. Chem. Soc., 91, 1528 (1969).

    Google Scholar 

  3. Koniklijke Nederlandishe Gist-en Spiritus-Fabriek N. V., Dutch Patent No. 2107650; Chem. Abstr., 76, 3879 (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga

    G. A. Veinberg, E. M. Belevich & É. Ya. Lukevits

Authors
  1. G. A. Veinberg
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. M. Belevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. É. Ya. Lukevits
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 649–651, May, 1982.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Veinberg, G.A., Belevich, E.M. & Lukevits, É.Y. Structure of 6-β-[(hexahydro-1H-azepin-1-yl)methyleneamino]penicillanic acid sulfoxide. Chem Heterocycl Compd 18, 489–491 (1982). https://doi.org/10.1007/BF00526083

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00526083

Keywords

Search

Navigation