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Some aspects of the thermodynamics of very dilute nonelectrolyte solutions

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Abstract

Deductions from phenomenological thermodynamics and schematic molecular-kinetic concepts are compared with experiment to explain the constancy of partial molar quantities and of the relative fugacity in the Henry region. The result is of considerable importance to purification by rectification.

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References

  1. J. W. Gibbs, Thermodynamic Papers [Russian translation], Gostekhlzdat, Moscow-Leningrad, 1950.

    Google Scholar 

  2. P. Duhem, Compt. rend de l'Acad. Sci., Paris, 102, 1449, 1886.

    Google Scholar 

  3. I. R. Krichevskii, Phase Equilibria in Solutions at High Pressures [in Russian], Goskhimizdat, Moscow-Leningrad, 1952.

    Google Scholar 

  4. V. V. Krapukhin and V. N. Chernyaev, Izv. VUZ. Tsvetnaya Metallurgiya, no. 6, 124, 1960.

    Google Scholar 

  5. V. N. Chernyaev, V. V. Krapukhin, and Yu. M. Martynov, Izv. VUZ. Tsvetnaya Metallurgiya, no. 8, 56, 1961.

    Google Scholar 

  6. L. A. Nisel'son and I. I. Lapidus, ZhFKh, 39, 161, 1965.

    Google Scholar 

  7. V. B. Kogan, Azeotropic and Extractive Rectification [in Russian], Goskhimizdat, Leningrad, 1961.

    Google Scholar 

  8. K. Akerman, M. Brafman, O. Kruszewska, and K. Kruszewski, Przeglad Elektroniki, no. 5–6, 299, 1963.

    Google Scholar 

  9. B. D. Stepin, G. Z. Blyum, and M. M. Shvarts, Khim. Prom., no. 2, 138, 1963.

    Google Scholar 

  10. E. Erdös, Chem. Listy, 47, 641, 1953; Coll. Czech. Chem. Comm., 18, 727, 1953.

    Google Scholar 

  11. E. Hala, J. Pik, V. Frid, and O. Vilim, Liquid-Vapor Equilibrium [Russian translation], IIL, Moscow, 1962.

    Google Scholar 

  12. Reinstoffe in Wissenschaft und Technik, Inter. Symp., Dresden, 1961, Berlin, Akad. Verlag, 1963.

  13. Ya. D. Zel'venskii and V. A. Shalygin, Khim. Prom., no. 5, 41, 1962.

    Google Scholar 

  14. Ya. D. Zel'venskii and A. A. Efremov, Proceedings of the Conference on Methods of Making Ultrapure Substances [in Russian], Trudy IREA Khimiya, no. 31, 1967.

  15. D. N. Lewis and M. Randall, Chemical Thermodynamics [Russian translation], Goskhimizdat, Moscow-Leningrad, 1949.

    Google Scholar 

  16. M. Kh. Karapet'yants, Chemical Thermodynamics [in Russian], Goskhimizdat, Moscow-Leningrad, 1949.

    Google Scholar 

  17. M. S. Vrevskii, A Study of Solutions at Various Temperatures [in Russian], Petrograd, 1916.

  18. Van Laar, Z. phys. Chem., 15, 457, 1894.

    Google Scholar 

  19. M. Margules, Sitzungsber. Akad. Wiss. Wien Math. Naturwiss, K. II, 104, 1243, 1895.

    Google Scholar 

  20. E. A. Melvin-Hughes, Physical Chemistry [Russian translation], vol. 1, IIL, Moscow, 1962.

    Google Scholar 

  21. A. M. Dlin, Mathematical Statistics in Technology [in Russian], Sovetskaya Nauka, Moscow, 1958.

    Google Scholar 

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Authors and Affiliations

  1. All-Union Reagents and Ultrapure Substances Research Institute, Moscow

    B. D. Stepin & G. Z. Blyum

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  1. B. D. Stepin
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  2. G. Z. Blyum
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Stepin, B.D., Blyum, G.Z. Some aspects of the thermodynamics of very dilute nonelectrolyte solutions. Theor Exp Chem 4, 66–68 (1970). https://doi.org/10.1007/BF00525950

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