Abstract
The characteristics of these ions and radicals are calculated with the use of the additional parameters k=0.7 and h=1,2,3. This model corresponds with experiment and with theoretical concepts of hydrocarbon chemistry; it explains some aspects of arylolefin reactions.
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References
Yu. N. Polovoi and D. M. Kuz'menkov, Vestnik LGU, No. 22, issue 4, 138, 1965.
J. P. Kennedy, C. A. Cohen, W. Naegele, J. Pol. Sci., B2, 1159, 1964.
Yu. N. Polovoi and V. P. Efimov, ZhPKh, 38, 449, 1965.
O. A. Reutov, Theoretical Problems of Organic Chemistry [in Russian], Izd. MGU, ch. 4. 1956.
E. Streitwieser, Molecular Orbital Theory for Organic Chemists [Russian translation], Moscow, Mir, ch. 12, 1965.
B. G. Brooks, et al., The Chemistry of Petroleum Hydrocarbons [Russian translation], Gostoptekhizdat, vol. 2, ch. 27, 1958.
Ibid., ch. 26.
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Polovoi, Y.N., Kuz'menkov, D.M. A heteroatomic model of the alkyl groups in the ions and radicals formed from isomeric phenylpropenes. Theor Exp Chem 3, 170–174 (1969). https://doi.org/10.1007/BF00525591
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DOI: https://doi.org/10.1007/BF00525591