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An infrared spectroscopic study of the reaction of alcohols and their decomposition products with yttrium oxide

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Abstract

This paper describes an infrared spectroscopic study of the adsorption of methanol, ethanol, acetaldehyde, ethylene, and water on two samples of yttrium oxide, one of which had dehydrating properties and the other, dehydrogenating properties. The occurrence of different surface compounds during the dehydration and dehydrogenation of alcohols is shown. Possible mechanisms for the decomposition of alcohols are discussed.

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References

  1. A. N. Terenin, ZhFKh, 14, 1362, 1940.

    Google Scholar 

  2. A. N. Terenin, in: Surface Chemical Compounds and their Role in Adsorption Phenomena [in Russian], Moscow State University, 1957; R. P. Eischens and W. A. Pliskin, Adv. in Catalysis, 10, 1, 1958; A. V. Kiselev and V. I. Lygin, Usp. khim., 31, 351, 1962.

  3. A. A. Tolstopyatova et al., Kinetika i kataliz, 2, 135, 1961.

    Google Scholar 

  4. M. K. Krasil'nikova, I. F. Moskovskaya, and K. V. Topchieva, in: Interior Mechanism of Catalytic Reactions [in Russian], Izd-vo AN SSSR, 1966; Summary of Catalytic Reactions [in Russian], Moscow, 1964.

  5. K. V. Topchieva and V. Ya. Stetsenko, Kinetika i Kataliz, 6, 1965.

  6. V. I. Lygin et al., ZhFKh, 35, 932, 1961.

    Google Scholar 

  7. E. G. Boreskova et al., Kinetika i kataliz, 5, 1115, 1964.

    Google Scholar 

  8. P. A. Howell, J. Phys. Chem., 64, 364, 1960.

    Google Scholar 

  9. A. V. Kiselev and V. I. Lygin, Kolloidnyi zhurnal, 21, 581, 1959.

    Google Scholar 

  10. K. A. Wickersheim and R. A. Lefever, J. Opt. Soc. Am., 51, 1147, 1961.

    Google Scholar 

  11. A. Duval, Anal. Chim. Acta, 10, 321, 1954.

    Google Scholar 

  12. G. V. Yukhnevich, Usp. khim., 32, 1397, 1963.

    Google Scholar 

  13. R. G. Greenler, J. Chem. Phys., 37, 2094, 1962; Spectrochim. Acta, 18, 1385, 1962.

    Google Scholar 

  14. W. West, (ed.), Chemical Applications of Spectroscopy [Russian translation], Moscow, IL, 1959; L. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], Moscow, IL, 1957.

    Google Scholar 

  15. A. A. Babushkin and A. V. Uvarov, DAN USSR, 110, 581, 1956.

    Google Scholar 

  16. Yu. M. Shchekochikhin et al., Kinetika i kataliz, 5, 113, 1964.

    Google Scholar 

  17. L. M. Roev and A. N. Terenin, DAN USSR, 124, 373, 1959.

    Google Scholar 

  18. Yu. M. Shchekochikhin, Dissertation, Novosibirsk, 1964.

  19. G. I. Jenkins and E. K. Rideal, J. Chem. Soc., 2490, 1955.

  20. G. Stegner et al., Izv. AS USSR, OKhN, 1896, 1959.

  21. J. B. Peri, J. Phys. Chem., 69, 211, 1965.

    Google Scholar 

  22. K. V. Topchieva and K. Yung P'ing, Zh. F. Kh., 29, 2077, 1955.

    Google Scholar 

  23. K. V. Topchieva et al., collection: Surface Chemical Compounds and their Role in Adsorption Phenomena [in Russian], Moscow State University, 311, 1957.

  24. F. F. Vol'kenshtein, Electronic Theory of Catalysis [in Russian], Fizmatgiz, 1960.

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Krasil'nikova, M.K., Lygin, V.I. & Topchieva, K.V. An infrared spectroscopic study of the reaction of alcohols and their decomposition products with yttrium oxide. Theor Exp Chem 2, 67–72 (1967). https://doi.org/10.1007/BF00524259

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  • DOI: https://doi.org/10.1007/BF00524259

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