Skip to main content
SpringerLink
Log in

Radical products of the thermal decomposition of ionol hydroperoxide

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

It has been shown that the thermal decomposition of 4-hydroperoxy-4-methyl-2, 6-ditert-butylcyclohexadien-2, 5-one is accompanied by the rupture of the C-O bond in the COOH group, with the formation of 2, 6-ditert-butyl-4-methylphenoxyl radicals. On the basis of the electronic paramagnetic resonance spectra, it has been found that transfer of hydrogen occurs from the diphenylamine molecule and those of sterically hindered phenols to the radicals of 2, 6-ditert-butyl-4-methylphenoxyl radicals formed by the decomposition of the hydroperoxide.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. R. Gersmann and A. F. Bickel, J. Chem. Soc., 2711, 1959.

  2. H. R. Gersmann and A. F. Bickel, J. Chem. Soc., 2359, 1962.

  3. I. I. Conradi and G. A. McLaren, J. Am. Chem. Soc., 82, 4745, 1960.

    Google Scholar 

  4. V. D. Pokhodenko, L. N. Ganyuk, and A. I. Brodskii, DAN SSSR, 149, 321, 1963.

    Google Scholar 

  5. G. D. Cook, D. A. Kuhn, and P. Fianu, J. Am. Chem. Soc., 78, 2002, 1956.

    Google Scholar 

  6. A. V. Karyakin, Dissertation, MGU, Moscow 1958; M. A. Kovner, A. V. Karyakin, and A. P. Efimov, Opt. i spektr., 8, 128, 1960.

    Google Scholar 

  7. A. V. Karyakin, V. A. Nikitin, and K. I. Ivanov, ZhFKh, 27, 1856, 1953.

    Google Scholar 

  8. A. V. Tobolsky and R. B. Mesrobian, Organic Peroxydes, N. J., 1954.

  9. A. I. Brodskii, V. D. Pokhodenko, and L. N. Ganyuk, Rozniki Chemii, 38, 105, 1964.

    Google Scholar 

  10. A. L. Buchachenko, Stable Radicals [in Russian], Izd-vo AN SSSR, p. 89, 1963.

  11. K. Scheffler, Z. Analyt, Chem., 181, 456, 1961.

    Google Scholar 

  12. E. Müller, K. Ley, W. Scheffler, and K. Mayer, Chem Ber., 91, 2682, 1958.

    Google Scholar 

  13. J. M. Turner, J. Phys. Chem. 65, 2114, 1961.

    Google Scholar 

  14. E. R. Altwicker, C. D. Cook, and N. D. Gilmor, Tetr. Lettr., 721, 1963.

  15. V. D. Pokhodenko, Dissertation, Kiev, 1953.

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, AS UkrSSR, Kiev

    V. D. Pokhodenko & V. A. Bidzilya

Authors
  1. V. D. Pokhodenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Bidzilya
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pokhodenko, V.D., Bidzilya, V.A. Radical products of the thermal decomposition of ionol hydroperoxide. Theor Exp Chem 1, 540–543 (1967). https://doi.org/10.1007/BF00524042

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00524042

Keywords

Search

Navigation