This is a preview of subscription content, log in via an institution to check access.
Literature cited
V. D. Pokhodenko, A. A. Beloded, and V. G. Koshechko, Free-Radical Redox Reactions [in Russian], Naukova Dumka, Kiev (1977).
A. J. Bard, A. Ledwith, and H. J. Shine, “Formation, properties and reactions of cation radicals in solution,” Adv. Phys. Org. Chem., 13, 155–278 (1976).
V. A. Krylov, V. G. Koshechko, and V. D. Pokhodenko, “A study of the effects from the dielectric constant of an organic solvent on the degree of association for cation-radical salts of various aromated amines,” Zh. Fiz. Khim., 56, No. 10, 2538–2543 (1982).
V. G. Koshechko, V. A. Krylov, and V. D. Pokhodenko, “The effects of solvation and ionic association on the absorption spectra of cation-radical salts of substituted triphenylamines,” Teor. Éksp. Khim., 18, No. 3, 313–318 (1982).
V. G. Koshechko, V. A. Krylov, and V. D. Pokhodenko, “A conductometric study of the effects of the nature of the medium on the dissociation of the cation-radical salt of tri-p-tolylamine,” Zh. Fiz. Khim., 55, No. 5, 1288–1291 (1981).
M. Swarcz (editor), Ions and Ion Pairs in Organic Reactions, Krieger (1972).
B. A. Kowert, L. Marcoux, and A. J. Bard, “Homogeneous electron-transfer reactions of several aromatic anion and cation radicals,” J. Am. Chem. Soc., 94, No. 16, 5538–5550 (1972).
S. P. Sorensen and W. H. Bruning, “Ion-pairing effects on electron transfer rate constants by electron spin resonance fast exchange line-width studies. Application to tri-p-tolylamine and phenothiazine cation systems,” J. Am. Chem. Soc., 95, No. 8, 2445–2451 (1973).
J. E. Wertz and J. R. Bolton, Electron Spin Resonance: Elementary Theory and Practical Applications, McGraw-Hill (1972).
I. C. Lewis and L. S. Singer, “Electron spin resonance of radical cations produced by the oxidation of aromatic hydrocarbons with SbCl5,” J. Chem. Phys., 43, No. 8, 2712–2727 (1965).
L. H. Piette and W. A. Anderson, “Potential-energy barrier determinations for some alkyl nitrites by nuclear magnetic resonance,” J. Chem. Phys., 30, No. 3, 899–908 (1959).
V. S. Kuts and Yu. A. Kruglyak, “Analysis of resolved ESR spectra for free radicals,” Zh. Strukt. Khim., 9, No. 3, 411–417 (1968).
V. S. Kuts and Yu. A. Kruglyak, “Analysis of poorly resolved ESR spectra for free radicals,” in: Radio-Spectroscopy and Quantum-Chemical Methods in Structural Research [in Russian], Nauka, Moscow (1967), pp. 80–84.
A. Streitwieser, Molecular Orbital Theory for Organic Chemists, Wiley (1961).
J. E. Bloor, B. R. Gilson, R. J. Haas, and C. L. Zinkle, J. Med. Chem., 13, No. 5, 922–925 (1970).
E. T. Seo, R. F. Nelson, J. M. Fritsch, et al., “Anodic oxidation pathway of aromatic amines. Electrochemical and electron paramagnetic resonance studies,” J. Am. Chem. Soc., 88, No. 15, 3498–3503 (1966).
H. Reichardt, Solvents in Organic Chemistry [Russian translation], Khimiya, Leningrad (1973).
V. D. Pokhodenko, V. G. Koshechko, and V. A. Krylov, “Thermodynamics of ion-pair equilibrium for a series of cation-radical salts in acetonitrile and chlorobenzene,” Zh. Fiz. Khim. (1983), in press.
V. G. Koshechko, V. A. Krylov, and V. D. Pokhodenko, “Thermodynamics of the dissociation of stable cation-radical salts in dichloroethane and mixtures of this with carbon tetrachloride,” Zh. Fiz. Khim. (1983), in press.
R. A. Marcus, “On the theory of electron-transfer reaction. 4. Unified treatment for homogeneous and electrode reaction,” J. Chem. Phys., 43, No. 2, 679–701 (1965).
K. Suga and Sh. Aoyagui, “The applicability of the theory of R. A. Marcus to the electron-transfer reactions between polycyclic aromatic hydrocarbons and their anion radicals,” Bull. Chem. Soc. Jpn., 46, No. 3, 755–761 (1973).
K. Suga, Sh. Ishikawa, and Sh. Aoyagui, “The dependence of the electron-transfer rates of aromatic hydrocarbon anion radicals upon the molecular radii of the reactants,” Bull. Chem. Soc. Jpn., 46, No. 3, 808–812 (1973).
L. Sutton, “Tables of the interatomic distances and configuration in molecules and ions,” The Chem. Soc., Burlington House, London, W.l, No. 11 (1958).
Author information
Authors and Affiliations
Additional information
Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 19, No. 2, pp. 161–169, March–April, 1983.
Rights and permissions
About this article
Cite this article
Koshechko, V.G., Titov, V.E. & Pokhodenko, V.D. Effect of reagent structure and nature of medium on the kinetics of electron exchange between substituted triphenylamine cation radicals and the corresponding neutral molecules. Theor Exp Chem 19, 143–150 (1983). https://doi.org/10.1007/BF00522418
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00522418