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Anhydro bases of the pyridine series (review)

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Methods for the preparation of anhydro bases of the pyridine series by deprotonation of the corresponding quaternary salts under the influence of bases, as well as by the direct reaction of quaternary pyridinium or halopyridinium salts with CH acids in the presence of bases, are examined. The reactions of anhydro bases with various reagents (alkyl cations, acylium cations, the proton, aldehydes, isothiocyanates, carbon disulfide, the hydroxide ion, etc.), which constitute evidence for their high reactivities, are examined. The participation of anhydro bases as intermediates in many reactions intended for the preparation of new heterocyclic systems is demonstrated.

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Authors and Affiliations

  1. Donetsk State University, 350055, Donetsk

    T. V. Stupnikova, B. P. Zemskii, R. S. Sagitullin & A. N. Kost

  2. M. V. Lomonosov Moscow State University, 117234, Moscow

    T. V. Stupnikova, B. P. Zemskii, R. S. Sagitullin & A. N. Kost

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  1. T. V. Stupnikova
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  2. B. P. Zemskii
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  3. R. S. Sagitullin
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Deceased.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No.3, pp. 291–311, March, 1982.

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Stupnikova, T.V., Zemskii, B.P., Sagitullin, R.S. et al. Anhydro bases of the pyridine series (review). Chem Heterocycl Compd 18, 217–232 (1982). https://doi.org/10.1007/BF00522116

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